『Abstract
A new classification and nomenclature scheme for the amphibole-supergroup
minerals is described, based on the general formula AB2C5T8O22W2, where A = □, Na, K, Ca, Pb, Li; B = Na, Ca,
Mn2+, Fe2+, Mg, Li; C = Mg, Fe2+,
Mn2+, Al, Fe3+, Mn3+, Ti4+,
Li; T = Si, Al, Ti4+, Be; W = (OH), F, Cl, O2-.
Distinct arrangements of formal charges at the sites (or groups
of sites) in the amphibole structure warrant distinct root names,
and are, by implication, distinct species; for a specific root
name, different homovalent cations (e.g., Mg vs. Fe2+)
or anions (e.g., OH vs. F) are indicated by prefixes (e.g., ferro-,
fluoro-). The classification is based on the A, B, and C groups
of cations and the W group of anions, as these groups show the
maximum compositional variability in the amphibole structure.
The amphibole supergroup is divided into two groups according
to the dominant W species: W(OH,F,Cl)-dominant amphiboles
and WO-dominant amphiboles (oxo-amphiboles). Amphiboles
with (OH, F, Cl) dominant at W are divided into eight subgroups
according to the dominant charge-arrangements and type of B-group
cations: magnesium-iron-manganese amphiboles, calcium amphiboles,
sodium-calcium amphiboles, sodium amphiboles, lithium amphiboles,
sodium-(magnesium-iron-manganese) amphiboles, lithium-(magnesium-iron-manganese)
amphiboles and lithium-calcium amphiboles. Within each of these
subgroups, the A- and C-group cations are used to assign specific
names to specific compositional ranges and root compositions.
Root names are assigned to distinct arrangements of formal charges
at the sites, and prefixes are assigned to describe homovalent
variation in the dominant ion of the root composition. For amphiboles
with O dominant at W, distinct root-compositions are currently
known for four (calcium and sodium) amphiboles, and homovalent
variation in the dominant cation is handled as for the W(OH,F,Cl)-dominant
amphiboles. With this classification, we attempt to recognize
the concerns of each constituent community interested in amphiboles
and incorporate these into this classification scheme. Where such
concerns conflict, we have attempted to act in accord with the
more important concerns of each community.
Keywords: amphibole; nomenclature; classification; chemical composition;
crystal chemistry』
Introduction
General statement
The new classification
Amphibole classification by chemical formula
Significant issues involved in the classification of amphiboles
Root names
Prefixes
Adjectival modifiers
Named amphiboles
Synthetic amphiboles
Other issues
The principal variables used in the classification procedure
A new scheme for the classification of amphiboles
Amphiboles with (OH, F, Cl) dominant at W
The magnesium-iron-manganese amphiboles
The calcium amphiboles
The sodium-calcium amphiboles
The sodium amphiboles
The lithium amphiboles
The sodium-(magnesium-iron-manganese) amphiboles
The lithium-(magnesium-iron-manganese) amphiboles
The lithium-calcium amphiboles
Amphibole with O2- dominant at W
Coda
References cited
Appendix I: The C2/M amphibole structure
Appendix II: The role of Fe, H, and Li
Appendix III: Calculation of Fe3+ and (OH) in amphiboles
Calculation of amphibole formulas and (OH) content
Calculation of amphibole formulas and Fe3+ content
General points
Calculation procedures
Appendix IV: Principal variables used in the classification procedure
The W anions
Hydroxy-fluoro-chloro-amphibole group
Problems with the previous amphibole classification
(1) The role of BLi
(2) The names of the principal subgroups
The new classification
(1) The role of the sodium-calcium, lithium-calcium, sodium-(magnesium-iron-manganese),
and lithium-(magnesium-iron-manganese) subgroups
(2) Lithium-calcium, sodium-(magnesium-iron-manganese), and
lithium-(magnesium-iron-manganese) subgroups
(3) The A cations
(4) The C cations
Appendix V: Major differences between the new classification and
IMA1997 and IMA2003
Appendix VII: Symbols and amphiboles