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wiAbstractj
@The regional distribution of heavy metal elements (V, Cr, Mn,
Co, Ni, Cu, Zn, As, Mo, Cd, Sn, Sb, W, Pb, Bi, etc.) was investigated
by using X-ray fluorescent spectrometer and ICP-MS for the stream
sediments from the Ashida River system in the eastern part of
Hiroshima Prefecture.
@In main stream sediments, systematic change in the concentration
of heavy metal elements from upper to lower reaches was not recognized.
Local abnormality on the concentration of Sn and W, however, were
found in the stream sediments at middle reaches. On the other
hand, branch stream sediments are generally rich in Cu, Zn, Cd,
As and Pb. Of them, the concentration of Zn, Cd and Pb are much
higher. Especially, the concentration of Cd reach about 30 ppm
in maximum, which is comparable to that of once reported in the
stream sediments of the Jinzu River, Toyama Prefecture, being
well-known as Itai-Itai disease. Consequently, it follows that
some of branch stream sediments were heavily polluted by heavy
metals.
@There exist many Cu, Zn, Pb and W mines in study area, where
had once operated. The high concentration of Cd in branch stream
sediments seems to be originated by Zn deposits composed mainly
of sphalerite with minor amount of Cd. Furthermore, the high concentration
of Pb and Cu are likely to be responsible for the metalliferous
deposits. As for the local abnormality n concentration of Sn and
W in main stream sediments, corresponding mines could not find.
Therefore, potential vein-type deposits of Sn and W in surrounding
granitic rocks may be their origin.x