『Abstract
Manganese carbonate deposits in Japanese Jurassic sedimentary
rocks were studied petrogeochemically. The deposits are characteristically
composed of spheroidal micronodules, up to 1 mm in diameter, and
always contain well-preserved radiolarian shells. Chemical elemental
composition and mineralogical characteristics indicate that the
micronodules contain rhodochrosite in a mixed carbonate phase
composition (Mn86.7-92.2Ca2.2-2.9Mg2.6-6.7Fe2.6-5.6)CO3. Carbon and oxygen isotope values, which range
from -7.99 to -4.78‰ and -4.05 to 0.28‰ relative to PDB, respectively,
suggest that the manganese carbonate was precipitated in a suboxic
zone. The micronodules closely resemble agglutinated benthic foraminifera
in shape. We suggest that agglutinated foraminiferal tests composed
of radiolarian shells accumulated selectively on the sediment
surface during redeposition of bottom sediments and were replaced
by manganese carbonate in suboxic diagenetic conditions of manganese
reduction.』
Introduction
Geological setting
Experimental methods and results
Texture
Mineralogy
Electron microprobe analysis
Chemical analysis
Oxygen and carbon isotope composition
Discussion
Petrology and chemistry of manganese carbonate
Depositional environment of manganese carbonate
Origin of the micronodules
Conclusions
Acknowledgments
References