『Abstract
Mineral weathering is the primary source of long-term buffering
capacity in soils and is important for forest nutrient sustainability.
Regional assessments of weathering rates in Canada and the U.S.
have employed an empirical clay-based Soil Texture Approximation
(STA) owing to limited data availability, although the STA is
rarely calibrated before application to a study area. Soil weathering
rates estimated with the STA at 75 sites in Canadian forests (6-367
eq ha-1 year-1) were on average seven times
lower than estimates obtained using the PROFILE model and when
mineralogy was not available, the Analysis to Mineralogy model
and parameter estimation (143-2,119 eq ha-1 year-1).
Comparison with a catchment mass balance at a subset of sites
in Ontario (n=19) demonstrated the reliability of PROFILE weathering
estimates. A revised (generalized) STA model for total base cation
weathering was developed at the 75 study sites to incorporate
soil silt content (%) and loss-on-ignition (LOI,%) (BCw = 1.734+0.03・silt−0.06・LOI)・1,000・depth).
The model performance (Radj2=73%)
and relative bias (−1%) suggested that the revised STA may have
broad application to forest soils in Canada but may not necessarily
be suited to all soil texture classes.
Keywords: Canada; Forest soil; Mineralogy; PROFILE; Soil texture;
Weathering』
Introduction
Materials and methods
Study area
Data collection
Weathering rate estimation
PROFILE
Analysis to Mineralogy and parameter estimation
Soil Texture Approximation
Mass balance
Revised Soil Texture Approximation
Results
Mineralogy estimation
Soil Texture Approximation
Mass balance
Revised Soil Texture Approximation
Discussion
Mineralogy estimation
Evaluation of the Soil Texture Approximation
Revised Soil Texture Approximation
Further research and model improvement
Conclusions
Acknowledgments
References