『Abstract
The Miocene dolomite-chert microbialites studied here offer a
complete record of the geochemical cycles of silicate weathering
and the subsequent formation of secondary products. The microbialites
were formed in lacustrine systems during the Miocene of the Duero
Basin, central Spain. Mineralogical, chemical and petrographic
results provide evidence of the mediation of microbes in early
weathering and by-product formation processes. Irrespective of
the composition, the surfaces of the grains were subject to microbial
attachment and concomitant weathering. Palaeo-weathering textures
range from surface etching and pitting to extensive physical disaggregation
of the minerals. Extreme silicate weathering led to the complete
destruction of the silicate grains, whose prior existence is inferred
from pseudomorphs exhibiting colonial textures like those recognized
in the embedding matrix. Detailed petrographic and microanalytical
examinations of the weathering effects in K-feldspars show that
various secondary products with diverse crystalinity and chemical
composition can coexist in the interior of a mineral. The coexistence
of by-products is indicative of different microenvironmental conditions,
likely created by microbial reactions. Thus, the presence of varied
secondary products can be used as a criterion of biogenicity.
Intensive alteration of P-bearing feldspars suggests that mineral
weathering may have been driven by the nutrient requirements of
the microbial consortium involved in the precipitation of dolomite.
The rock record provides useful information on mineral weathering
mediated by microbes.
Keywords: silicate dissolution; microbial weathering; biomineralization;
lake; dolomite
1. Introduction
2. Geological and sedimentary setting
3. Material and methods
4. Results
4.a. Dolostone: petrographic features and microbial origin
4.b. Silicate occurrences and composition
4.c. The silicate - matrix interface
4.d. Weathering features on silicates
4.d.1. Quartz weathering
4.d.2. Phyllosilicate weathering
4.d.3. Plagioclase weathering
4.d.4. K-feldspars weathering
4.e. Vanished silicates in dolostone and chert beds
5. Discussion
5.a. Evidence for microbial involvement in the weathering
processes
5.b. Secondary products
5.c. Silicate composition and weathering sequence
6. Conclusions
Acknowledgements
References