『Abstract
This work is aimed at investigating the weathering processes
of the granodiorites cropping out in a small catchment of the
Sila Massif. The mineral constituents in this granodiorite are
plagioclase, often zoned with a Ca-rich core and a Na-rich rim,
quartz, chlorite, K-feldspar, white mica and epidote. During this
study, dolomite was discovered in local stream sediments, as separate
monomineralic grains, probably resulting from erosion of veins
cutting the crystalline rocks. Prevailing dissolution of foreign
dolomite and a Ca-rich plagioclase is suggested by the Ca-Mg-HCO3 chemical composition of local groundwaters and
stream waters, which is rather unexpected for waters interacting
with granitoid rocks. These qualitative observations are quantitatively
confirmed by reaction path modelling of the weathering processes
occurring in the study area, which was carried out using the EQ3/6
software package, version 8.0, and the Double Solid Reactant Method.
Indeed, it was possible to ascertain that the release of both
major dissolved constituents and several trace elements (Ba, Co,
Cr, Fe, Mn, Ni, Pb, Sr, V and Zn), from rocks to waters, is chiefly
controlled by the dissolution of foreign dolomite and the Ca-rich
core of zoned plagioclases.』
1. Introduction
2. Geological and pedological background
3. Methodology
3.1. Waters: sampling and analytical methods
3.2. Rocks and stream sediments: sampling and analytical methods
4. Results
4.1. Rock and mineral chemistry
4.2. Water chemistry
5. Reaction path modelling
5.1. Refurbishing the thermodynamic database
5.2. The solid reactants
5.3. The initial aqueous solution
5.4. The T-fCO2-redox
conditions
6. Results of reaction path modelling
6.1. The choice of alkalinity as proxy for the reaction progress
variable
6.2. The solid reactants
6.3. The solid products
6.4. The aqueous solution
6.4.1. Magnesium
6.4.2. Calcium
6.4.3. Silica
6.4.4. Strontium, barium and lead
7. Considerations on the stoichiometry of plagioclase dissolution
8. Conclusions and implications
Acknowledgements
References