『Abstract
The behaviour of major and trace elements have been studied along
two serpentinite weathering profiles located in the Kongo-Nkamouna
and Mang North sites of the Lomie(eの頭に´)
ultramafic complex.
The serpentinites are characterized by high SiO2
and MgO contents, very low trace, rare earth and platinum-group
element contents. Lanthanide and PGE contents are higher in the
Nkamouna sample than in Mang North. Normalized REE patterns according
to the CI chondrites reveal that : (i) all REE are below chondrites
abundances in the Mang North sample; (ii) the (La/Yb)N
ratio value is higher in the Nkamouna sample (23.72) than in the
Mang one (1.78), this confirms the slightly more weathered nature
of the Nkamouna sample. Normalized PGE patterns according to the
same CI chondrites reveal a negative Pt anomaly in the Mang sample.
The Nkamouna sample is characterized by a flat normalized PGE
pattern.
All element contents increase highly from the parent rock to
the coarse saprolite.
In the weathering profiles, Fe2O3
contents decrease from the bottom to the top contrarily to Al2O3, SiO2
and TiO2. The contents of alkali and alkaline
oxides are under detection limit.
Concerning trace elements, Cr, Ni, Co, Cu, Zn and Sc decrease
considerably from the bottom to the top while Zr, Th, U, Be, Sb,
Sn, W, Ta, Sr, Rb, Hf, Y, i, Ga, Nb and Pb increase towards the
clayey surface soil. Chromium, Ni and Co contents are high in
the weathered materials in particular in the saprolite zone and
in the nodules.
REE contents are high in the weathered materials, particularly
in Nkamouna. Their concentrations decrease along both profiles.
Light REE are more abundant than heavy REE. Normalized REE patterns
according to the parent rock reveal positive Ce anomalies in all
the weathered materials and negative Eu anomalies only at the
bottom of the coarse saprolite (Nkamouna site). Positive Ce anomalies
are higher in the nodular horizon of both profiles. An additional
calculation method of lanthanide anomalies, using NASC data, confirms
positive Ce anomalies ([Ce/Ce*]NASC
= 1.15 to 60.68) in several weathered materials except in nodules
([Ce/Ce*]NASC = 0.76) of the upper
nodular horizon (Nkamouna profile). The (La/Yb)N
ratios values are lower in the Nkamouna profile than in Mang site.
PGE are more abundant in the weathered materials than in the
parent rock.The highest contents are obtained in the coarse saprolite
and in the nodules. The elements with high contents along both
profiles are Pt (63-70 ppb), Ru (49-52 ppb) and Ir (41 ppb). Normalized
PGE patterns show positive Pt anomalies and negative Ru anomalies.
The mass balance evaluation, using thorium as immobile element,
reveals that:
- major elements have been depleted along the weathered profile,
except for Fe, Mn and Ti that have been enriched even only in
the coarse saprolite;
- all the trace elements have been depleted along both profiles,
except for Cr, Co, Zn, Sc, Cu, Ba, Y, Ga, U and Nb that have been
enriched in the coarse saprolite;
- rare earth elements have been abundantly accumulated in the
coarse saprolite, before their depletion towards the top of the
profiles;
- platinum-group elements have been abundantly accumulated in
the coarse saprolite but have been depleted towards the clayey
surface soil.
Moreover, from a pedogenetical point of view, this study shows
that the weathering profiles are autochtonous, except in the upper
part of the soils where some allochtonous materials are revealed
by the presence of zircon grains.
Keywords: Cameroon; Serpentinites; Laterites; Major elements;
Trace elements』
1. Introduction
2. Geographical and geological setting
3. Sampling and analytical procedures
4. Petrology of serpentinites
5. Petrology and major element geochemistry of weathered materials
5.1. Nkamouna weathering profile
5.2. Mang weathering profile
5.3. Comparison of the weathering profiles
6. Distribution of trace elements
7. Distribution, fractionation and normalization of REE
7.1. REE distribution and fractionation during weathering
processes
7.2. REE normalization
8. Distribution and normalization of PGE
8.1. PGE distribution
8.2. PGE normalization
9. Mass balance evaluation
10. Discussion
10.1. Petrology of serpentinites
10.2. Petrology and major element geochemistry
10.3. Behaviour of trace elements
10.4. Fractionation and normalization of REE
10.5. Behaviour of PGE
10.6. Mass balance evaluation
11. Conclusions
Acknowledgements
References