Traore(eの頭に´),D., Beauvais,A., Auge(eの頭に´),T., Parisot,J.-C., Colin,F. and Cathelineau,M.(2008): Chemical and physical transfers in an ultramafic rock weathering profile: Part 2.Dissolution vs. accumulation of platinum group minerals. American Mineralogist, 93, 31-38.

『超塩基性岩の風化断面における化学的および物理的移動:その2.白金族鉱物の溶解対集積』


Abstract
 The chemical weathering of ultramafic rocks has resulted in eluvial concentration of Pt-group minerals (PGM) in lateritic weathering profiles of southern New Caledonia. The Pt mineralization interpreted as being primary consists of Pt-group minerals included within chromite crystals. The occurrence of PGM as free particles in the weathering profile results from the supergene dissolution of Pt-bearing chromite (Traore(eの頭に´) et al. 2008). Following their release in the profile, supergene dissolution processes variably affect the PGM particles. The behavior of Pt-group elements in the weathering profile is characterized by significant loss of Pd and relative enrichment of Pt indicating that Pd is more mobile than Pt in the exogenous cycle. Unstable Pt-Fe-Cu-Pd alloys and PGE oxides undergo chemical and mineralogical changes to acquire the chemical configuration of isoferroplatinum (Pt3Fe), which is the most stable Pt phase in a lateritic environment. The isoferroplatinum phase may also be dispersed throughout the weathering mantle and/or accumulated in the lower parts of profiles according to a translocation mechanism of residual Pt-rich fine particles driven by percolation of water through the connected pore spaces.

Keywords: Platinum group minerals; platinum group elements; lateritic weathering; ultramafic rocks; New Caledonia』

Introduction
Geological and Geomorphological setting
Material and methods
Results and discussion
 Chemical and physical characterization of PGE and PGM
  PGE bulk chemistry
  PGM distribution and micromorphology
  Physical vs. chemical weathering signatures of PGM micromorphology
  PGM chemical analysis
 Selective dissolution of PGM
 Isoferroplatinum accumulation
Concluding statement
Acknowledgments
References cited


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