『Abstract
Conventional wisdom once held that weathering in cold climates
was overwhelmingly due to physical processes. However, that convention
was challenged when chemical weathering was identified, but unexplained,
as the dominant landscape denudation process in
Karkevagge(最初のaの頭に¨), an alpine valley
in Swedish Lapland. The research reported here involved scanning
electron microscopy and energy dispersive X-ray fluorescence of
rock coatings to investigate chemical weathering in Karkevagge(最初のaの頭に¨). Analyses revealed that white coatings
associated with streams emerging on the aluminum oxyhydroxide
sulfate such as basaluminite [Al4(SO4)(OH)10・H2O].
Efflorescence on seasonal vegetation in stream channels demonstrates
that this is an active process. The white coating chemistry exhibited
no systematic spatial patterns along the valley axis or with position
on the cliff face. Although the white coatings were not crystalline
and did not contain appreciable amounts of Fe or Cs, in sheltered
overhangs among boulders on the valley floor there were other
well-crystallized secondary sulfate minerals commonly associated
with pyrite oxidation, including gypsum, jarosite, and amorphous
Fe compounds. This difference is due presumably to the pH of the
associated waters, because Fe compounds tend to precipitate only
at pH<5, and Al compounds at pH>5, which is the pH of the stream
water. Pyrite oxidation nay be an important early weathering processes
in this and in many other environments. However, it largely goes
unrecognized because it occurs relatively rapidly in a geological
sense and typically is only identified in recently disturbed landscapes
associated with mining or other large-scale earth-moving activities.
Karkevagge(最初のaの頭に¨) demonstrates that subarctic
conditions do not preclude intense chemical weathering where conditions
are favorable, but it does not establish that strong chemical
weathering is a widespread attribute of subarctic conditions.
Keywords: weathering; pyrite; Sweden; Arctic; efflorescence; rock
coating; scanning electron microscopy』
Introduction
Research site
Methods and materials
Sampling
Scanning electron microscopy and elemental analyses
X-ray diffraction
Results and discussions
Scanning electron microscopy
Chemistry
Mineralogy
Spatial patterns
Stream samples
Lake Rissajaure Dam site, Cave of Wonders
Conclusions
Acknowledgments
References cited