Georg,R.B., Reynolds,B.C., West,A.J., Burton,K.W. and Halliday,A.N.(2007): Silicon isotope variations accompanying basalt weathering in Iceland. Earth and Planetary Science Letters, 261, 476-490.

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wAbstract
@This study presents the Si isotope compositions of the dissolved phase of twenty rivers from across Iceland. The high-resolution Nu Plasma 1700 MC-ICP-MS was used to provide interference-free 30Si/28Si ratios with an average limiting precision of }0.04ñƒÂ30Si. The Si isotope composition ranges from -0.08ñ to 1.46ñƒÂ30Si, averaging 0.63}0.38ñ(}1ƒÐSD). This is only slightly lighter than the recently reported mean of 0.84}0.19ñ for high precision measurements of Swiss rivers but is significantly lighter than compositions reported for some other rivers. The Si isotope composition varies slightly with the amount of glacial cover, which provides evidence that the continental Si input to the oceans may be climatically controlled and thus likely to vary over glacial-interglacial cycles. After correction for the dissolution of trace amounts of calcite in one region, a correlation id\s found between ƒÂ30Si and Ca/Si. This is consistent with the measured basaltic composition and indicates isotopic fractionation during Si removal from the dissolved phase. By calculating the fraction of Si that is removed from the dissolved phase into secondary phases it is possible to use the riverine Si flux (Si denudation rate) to calculate the initial dissolution rate of Si within these catchments. From this study we estimate that the total amount of Si being dissolved by primary weathering of Iceland is 3 million tons per yr. However only `50“ of this Si is released into the rivers and contribute to denudation. Using the Si isotope composition and the Si fraction removed, it is possible to model the Si isotope fractionation as either a Rayleigh-type fractionation or a steady-state system. Both yield similar fractionation factors of bout -1.5ñƒÂ30Si, implying only one underlying fractionation process that is controlled by external parameters, such as runoff. Furthermore, rivers that follow a steady-state fractionation model are associated with higher Si dissolution rates and lower ƒÂ30Si values, indicating an riverine relationship between weathering rates and dissolved riverine Si isotope composition.

Keywords: silicon; isotopes; weathering; Iceland; MC-ICP-MSx

1. Introduction
2. Climate and geology
3. Sampling and analytical methods
@3.1. Sample preparation
@3.2. Correction for wet depositional and hydrothermal inputs
@3.3. Silicon isotope measurement by MC-ICP-MS
4. Results
@4.1. Riverine aqueous chemistry
@4.2. Isotope composition of the dissolved riverine Si
5. Discussion
@5.1. Assessing the silicate derived weathering flux
@5.2. Variations of the elemental load and ƒÂ30Si
@5.3. Estimating Si removal
@5.4. Relative weathering mobility of Si
@5.5. Rayleigh-type vs. steady-state isotope fractionation
@5.6. Biotic vs. abiotic fractionation
@5.7. Controls on fsi and ƒÂ30Si
@5.8. Glacial-interglacial variations of riverine ƒÂ30Si
6. Conclusions
Acknowledgements
References


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