Hseu,Z.Y., Tsai,H., Hsi,H.C. and Chen,Y.C.(2007): Weathering sequences of clay minerals in soils along a serpentinitic toposequence. Clays and Clay Minerals, 55(4), 389-401.

『蛇紋岩質トポシーケンス(地形以外の条件がほぼ等しい地層)に沿う土壌中の粘土鉱物の風化シーケンス(系列)』


Abstract
 There has been limited research on clay mineral transformation in serpentinitic soils under humid tropical conditions. In this study, four soil pedons were selected along a toposequence from the summit (Entisol), shoulder (Vertisol), backslope (Alfisol) to footslope (Ultisol) positions to explore the contributions and the significance of landscape and weathering status of serpentinitic rock with regard to clay mineral transformations in eastern Taiwan. Experimental results indicated that the large amount of dithionite-citrate-bicarbonate-extractable Fe (Fed) and clay in the subsurface horizon were mainly caused by the strong leaching potential from intensive rainfall and weathering of the fine-grained parent rocks. The clay mineralogy reflected the clear weathering trend of the soils along the toposequence: (1) the soils on the summit and shoulder contained smectite and serpentine, which are predominant in the young soils derived from serpentinitic rocks; and (2) vermiculite gradually increased in the relatively old soils on backslope and footslope. The mineralogical transformations observed along the toposequence indicated that chlorite and serpentine, initially present in the Entisol on the summit, weather into smectite and interstratified chlorite-vermiculite in the intermediate soil on the shoulder under strong leaching and oxidizing conditions. Furthermore, vermiculite formed as the major weathering product of chlorite and smectite in the soil developed on the backslope. In addition to vermiculite, kaolinite and quartz formed in the soils on the footslope with the greatest concentration of Fed along the toposequence.

Key Words: Chlorite; Serpentine; Smectite; Soil taxonomy; Taiwan; Toposequence; Weathering sequence.』

Introduction
Materials and methods
 Site description
 Physical and chemical analysis
 Thin-section preparation and description
 X-ray diffraction of soil fraction and rock
 Thermogravimetric analysis
Results and discussion
 Parent materials and primary minerals
 Selected physical and chemical properties of the soil pedons
 Clay mineral compositions
 Mineral transformation during pedogenesis
Conclusions
Acknowledgments
References


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