『Abstract
Saline solution properties, viscosity in particular, are shown
to be critical in salt weathering associated with sodium and magnesium
sulfate crystallization in porous limestone. The crystallization
of sodium and magnesium sulfate within a porous limestone has
been studied at a macro- and microscale using different techniques,
including mercury intrusion porosimetry, environmental scanning
microscopy and X-ray computed tomography. Such analysis enabled
the visualization of the crystallization process in situ, and
at high magnification, yielding critical information as to where
and how salts crystallize. Sodium sulfate decahydrate (mirabilite)
tends to crystalline in large pores as euhedral micron-sized crystals
formed at low supersaturation near to the surface of the stone.
In contrast, magnesium sulfate heptahydrate (epsomite) tends to
precipitate as anhedral wax-like aggregates formed at high supersaturation
and distributed homogeneously throughout the stone pore system
filling large and small pores. While the former crystallization
behavior resulted in scale formation, the latter led to crack
development throughout the bulk stone. Ultimately, the contrasting
weathering behavior of the two sulfates is explained by considering
differences in flow dynamics of solutions within porous materials
that are mainly connected with the higher viscosity of magnesium
sulfate saturated solution (7.27 cP) when compared with sodium
sulfate saturated solution (1.83 cP). On the basis of such results,
new ways to tackle salt weathering, particularly in the field
of cultural heritage conservation, are discussed.
Keywords: Stone decay; Sodium sulfate; Magnesium sulfate; Salt
weathering; ESEM』
Introduction
Materials and methods
Studied salts
Stone characterization
Macroscale salt crystallization experiments
In situ ESEM microscale salt crysallization experiments
Results and discussion
Stone pore system and susceptibility to salt weathering
Macroscale salt crystallization tests: sodium sulfate
Macroscale salt crystallization tests: magnesium sulfate
Microscale crystallization tests: ESEM dynamic experiments
Role of solution properties on differential damage behavior of
sulfates
Conclusions
Acknowledgments
References