『Abstract
This work focuses on two possible sources of Hg in tropical soils,
(i) lithogenic Hg from in situ weathering of soil parental
material, and (ii) exogenic Hg from natural long-term atmospheric
inputs and anthropogenic input from past and present industrial
activities. The concentration of lithogenic Hg [Hg]lithogenic
was based on comparison of measured Hg concentration with those
of elements resistant to weathering such as Nb, U, Zn, Fe. Exogenic
Hg was quantified by subtracting [Hg]lithogenic
from total Hg concentrations. This calculation was applied to
4 French F\Guiana soil profiles, 3 profiles on the same toposequence
(ferralsol, acrisol, hydromorphic soil) and one acrisol close
to a Au mine, where elemental Hg is used. In all profiles, [Hg]lithogenic varied slightly and was always below
40μg kg-1, whereas [Hg]exogenic
varied considerably and reached 500μg kg-1. The highest
[Hg]exogenic was calculated for the upper
horizon of the acrisol close to Au mining activity, but also in
the ferralsol. Concentrations of Hg were insignificant in the
compact alterite in acrisols. It was concluded that pedogenesis
processes that affect the natural Hg supply, combined with anthropogenic
sources, explain the Hg concentrations in these tropical soils.』
1. Introduction
2. Materials and methods
2.1. Site and soil characteristics
2.2. Analyses
2.3. Enrichment factors and Hg origins calculations
3. Results
4. Discussion
4.1. Choice of reference material
4.2. Choice of invariant element
4.3. Choice of U, Zn and Fe as proxies for Hg
4.4. Enrichment factor calculations using Nb as an invariant
element
4.5. Lithogenic versus exogenic origin for Hg in the soil profiles
5. Conclusions
Acknowledgements
References