Guedron et al.(2006)による〔『Weathering versus atmospheric contributions to mercury concentrations in French Guiana soils』(2010p)から〕

『仏領ギアナにおける土壌中の水銀濃度に与える風化あるいは大気の影響』


Abstract
 This work focuses on two possible sources of Hg in tropical soils, (i) lithogenic Hg from in situ weathering of soil parental material, and (ii) exogenic Hg from natural long-term atmospheric inputs and anthropogenic input from past and present industrial activities. The concentration of lithogenic Hg [Hg]lithogenic was based on comparison of measured Hg concentration with those of elements resistant to weathering such as Nb, U, Zn, Fe. Exogenic Hg was quantified by subtracting [Hg]lithogenic from total Hg concentrations. This calculation was applied to 4 French F\Guiana soil profiles, 3 profiles on the same toposequence (ferralsol, acrisol, hydromorphic soil) and one acrisol close to a Au mine, where elemental Hg is used. In all profiles, [Hg]lithogenic varied slightly and was always below 40μg kg-1, whereas [Hg]exogenic varied considerably and reached 500μg kg-1. The highest [Hg]exogenic was calculated for the upper horizon of the acrisol close to Au mining activity, but also in the ferralsol. Concentrations of Hg were insignificant in the compact alterite in acrisols. It was concluded that pedogenesis processes that affect the natural Hg supply, combined with anthropogenic sources, explain the Hg concentrations in these tropical soils.』

1. Introduction
2. Materials and methods
 2.1. Site and soil characteristics
 2.2. Analyses
 2.3. Enrichment factors and Hg origins calculations
3. Results
4. Discussion
 4.1. Choice of reference material
 4.2. Choice of invariant element
 4.3. Choice of U, Zn and Fe as proxies for Hg
 4.4. Enrichment factor calculations using Nb as an invariant element
 4.5. Lithogenic versus exogenic origin for Hg in the soil profiles
5. Conclusions
Acknowledgements
References


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