『Abstract
This paper examines the surface sediments collected from Dongping
Lake in China for speciation and distribution of toxic heavy metals
(Cu, Pb, Ni, Cd) in different grain size fractions, and for the
factors that need to be considered in potential hazard of metals
to the environment. Four grain size fractions (<63, 63-78, 78-163
and 163-280μm), divided in wet condition, and bulk samples less
than 280μm in diameter were analyzed for their distribution, density
and appearance. A three-stage extraction procedure following the
BCR protocol was used to chemically fractionate metals into “acid
soluble”, “reducible”, “oxidizable” and “residual” fractions.
Correlation analysis was used to analyze the datasets. The results
showed that <63μm grain size part constitutes the major proportion
of the sediments, but its density is the smallest among the four
grain size fractions. In general, the metal content curve against
grain size presents “S” distribution, and the highest concentrations
do not exist in <63μm grain size. Appearance observation indicates
that the adsorbed substance increases gradually along with the
decreasing grain size. The dominant speciation of elements and
the extent of pollution are responsible for the metal distribution
in different grain size sediments. While studying bioavailability
and mobilization of metals, it is advisable to take metal speciation,
grain size distribution and density into consideration.
Keywords: Grain size; Sediments; Heavy metal; Speciation; Fractionation;
Dongping Lake; TEM』
Introduction
Materials and methods
Study area
Sampling and size fractionation
Chemical classification for heavy metals
Analytical method
Quality assurance
Results and discussion
Grain size distribution and density
The exterior characteristics of different grain size sediments
The variation regulation of heavy metal contents along with grain
size
Correlation analysis of total metal concentrations to metal speciation
Conclusions
References