『Abstract
Changes in the normative mineralogy and chemical weathering rates
(elemental loss) of Ca and Mg from the uppermost mineral soil
horizon were determined at five forested sites in the boreal zone
forming a chronosequence. The sites were all located on the same
glaciofluvial (esker) deposit (well-sorted sand) over a distance
of 27 km in the coastal region of the Gulf of Bothnia in Finland
and had estimated ages from 339 to 5276 years. Because of isostatic
land uplift the region is continually emerging from the sea, the
rates of which are known, allowing the age of current surfaces
to be dated. Soil profile development progressed from Gleyic Arenosols
(youngest and nearest the coast) through Haplic Arenosols to Haplic
Podzols (3 oldest and furthest away from the coast). Elemental
concentrations of soil (<2 mm) were determined using XRF and ICP-MS
from a hot aqua regia digest. Normative mineralogy was
determined using these data and a stoichiometric mineral distribution
model. Weathering (elemental loss) rates were calculated using
XRF concentrations and normative quartz as the conservative reference
component. Quartz was increasingly enriched in the uppermost horizon
with soil age, commensurate with the loss of easily weathered
minerals. Using quartz as the conservative component, the mass
residual fraction remaining in the uppermost soil horizon of the
oldest soil was 0.27, 0.35 and 0.57 respectively for biotite,
hornblende and anorthite, which are important sources of Ca and
Mg. B/E-horizon ratios of hydrous aluminosilicate contents increased
from 1 to 14 with soil age clearly indicating the increase in
degree of podzolisation. The losses of Ca and Mg increased with
soil age but at a decreasing rate. Ca and Mg losses for the youngest
soil were respectively 3.3 and 1.8 mol m-2; corresponding
values for the oldest soil were 10.6 and 10.5. Mean rates of loss
for the youngest soil were 10 and 5 mmol m-2 yr-1
for Ca and Mg respectively, and corresponding values for the oldest
soil were 2 mmol m-2 yr-1 for both Ca and
Mg. The loss of these base cations from the soil will have resulted
in a lower acid neutralizing capacity and increased sensitivity
of these soils to acidic deposition, and represents a reduction
in the soil reserve of important plant nutrients.
Keywords: Normative mineralogy; Soil formation; Base cations;
Gulf of Bothnia; Land uplift』
1. Introduction
2. Materials and methods
2.1. The chronosequence, soil age and sampling
2.2. Chemical analyses and calculation of normative mineralogy
2.3. Mineral and element weathering losses
3. Results
3.1. Elemental concentrations and soil normative mineralogy
3.2. Changes in normative mineralogy with soil age
3.3. Losses of soil material, Ca and Mg with soil age
4. Discussion
4.1. Methodological considerations
4.2. Normative mineral and elemental losses
5. Conclusions
Acknowledgements
References