Chevrie et al.(2006)による〔『Magnetic study of an Antarctic weathering profile on basalt: Implications for recent weathering on Mars』(501p)から〕

『玄武岩に対する南極風化断面の磁性研究:火星における現在の風化との関係』


Abstract
 In order to better interpret the Martian surface weathering-related mineralogy, we focused on a relevant analogue of the Martian subsurface i n terms of lithology and paleoclimate: the Jurassic-aged Ferrar dolerite (Priestley Glacier, Transantarctic Mountains), weathered in cold and dry climate. Together with chemical and mineralogical studies, rock magnetic properties were investigated and completed with Mossbauer(oの頭に¨) measurements. Weathering of the decimetric block is evidenced by chemical profiles showing an increase in Fe content (from 10.5 in the core to 13 wt.% in the surface) and a decrease in Si (from 57 to 53 wt.%, respectively). According to mineralogical, thermomagnetic and hysteresis properties, the main opaque mineral is inherited titanomaghemite, with a concentration about 1%. Enhancement in low field magnetic susceptibility (from 4・10-6 to 10・10-6 m3/kg, respectively) and saturation magnetization (from 0.44 to 0.96 Am2/kg, respectively) indicates the neoformation of metastable maghemite. Neoformed red ferric (oxy)hydroxides are abundant in the surface. High field susceptibility normalized to iron concentration and Mossbauer(oの頭に¨) spectra indicate a replacement of Fe2+ from primary silicates (pyroxene) by poorly crystalline antiferromagnetic Fe3+ (oxy)hydroxides. Thus, highly magnetic titanomaghemite and maghemite coexist with nanosized ferric (oxy)hydroxides and primary silicates, in accordance with Martian in situ observations. Therefore, this study supports the formation of the Martian regolith as resulting from a slow weathering process in near present day conditions.

Keywords: Antarctica; Ferrar dolerite; Mars; regolith; rock magnetism; weathering』

1. Introduction
2. Methods
 2.1. Sample description and preparation
 2.2. Rock magnetic properties
 2.3. Petrologic, mineralogical study and chemical analyses
3. Experimental results
 3.1. Chemical and mineralogical properties
  3.1.1. Bulk chemical analyses
  3.1.2. Observations with microscope and SEM
 3.2. Magnetic properties
  3.2.1. Low field magnetic susceptibility χLF and thermomagnetic properties
  3.2.2. High field magnetic susceptibility χHF
  3.2.3. Hysteresis properties
  3.2.4. Magnetic parameters normalized to iron content
 3.3. Mossbauer(oの頭に¨) spectroscopy
4. Discussion
 4.1. The magnetic phase in the Martian regolith
 4.2. Iron (oxy)hydroxides on Mars
5. Conclusions
Appendix A. Supplementary figure
References


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