『Abstract
This study presents Os isotope and comprehensive major and trace
element data for the dissolved load, suspended particulates and
bedload for Icelandic rivers, draining predominantly basaltic
catchments that range in age from historic to ca. 12 Ma. Hydrothermal
waters and precipitation have also been analysed. Both Os and
Re concentrations are greater in the suspended load than the bedload,
while Re/Os ratios are lower, suggesting that both elements are
concentrated in weathering resistant minerals. Despite this elemental
fractionation the suspended particulates and bedload for each
river yield indistinguishable 187Os/188Os
isotope compositions that range from 0.136 to 0.292. In contrast,
the dissolved load (<0.2μm filtered) often possesses a significantly
more radiogenic Os isotope composition than the corresponding
suspended or bed load with 187Os/188Os ratios
ranging from 0.15 to 1.04. The isotope and elemental data for
the dissolved load can be explained in terms of an unradiogenic
contribution from congruent basalt weathering (and/or hydrothermal
input) and a radiogenic contribution that arises from two distinct
processes. For the glacier-fed rivers there is a covariation between
187Os/188Os and the extent of glacial cover
in the catchment, and this is most readily explained by the entrainment
of seawater aerosols into precipitation and subsequent glacial
melting. While for direct-runoff (and spring-fed rivers) there
is a covariation between 187Os/188Os and
the age of the bedrock in the catchment, that cannot be explained
by congruent weathering of old basalt. Calculations indicate that
those direct-runoff rivers with radiogenic 187Os/188Os
values are also undersaturated with respect to the primary basalt
minerals olivine, pyroxene and plagioclase, indicating that these
phases are unstable and prone to preferential dissolution. Published
Re-Os isotope data indicate that the same phases possess exceptionally
high 187Os/188Os ratios and thus evolve
to radiogenic 187Os/188Os compositions in
very short time intervals. Taken together, these results indicate
that incongruent (preferential) weathering of certain primary
basalt minerals can impart a radiogenic Os isotope composition
to the dissolved riverine load. Nevertheless, overall the Os isotope
signal to the Oceans from Icelandic rivers is little affected
because rivers with unradiogenic 187Os/188Os
values and a high discharge dominate the Os flux.
Keywords: Re-Os isotopes; basaltic rivers; Iceland; weathering
susceptibility; saturation state; incongruent weathering』
1. Introduction
2. Climate, geology and hydrology
3. Field and analytical techniques
3.1. Sampling and storage
3.2. Anions, cations and trace elements
3.3. Re-Os analysis
3.3.1. Filtered river, rain and hot spring water
3.3.2. Oxidation duration
3.3.3. Suspended and bed load
4. Results
4.1. Suspended and bed load
4.2. Dissolved phase
4.3. Precipitation and geothermal water
5. Discussion
5.1. Re-Os isotope and elemental variations
5.2. Osmium isotope and elemental variations in the dissolved
load
5.3. Weathering susceptibility and saturation state
5.4. The Os isotope signature of primary basaltic minerals
5.5. The riverine osmium yield from basaltic terrains
6. Concluding remarks
Acknowledgements
Appendix A
Appendix B. Supplementary data
References