Lu et al.(2005)による〔『Element mobility during pyrite weathering: implications for acid and heavy metal pollution at mining-impacted sites』(82p)から〕

『黄鉄鉱風化の間の元素移動:鉱山による影響のある場所での酸性および重金属汚染との関係』


Abstract
 Based on back scattered electron images and electron microprobe analysis results, four alteration layers, including a transition layer, a reticulated ferric oxide layer, a nubby ferric oxide layer and a cellular ferric oxide layer, were identified in the naturally weathering products of pyrite. These layers represent a progressive alteration sequence of pyrite under weathering conditions. The cellular ferric oxide layer correlates with the strongest weathering phase and results from the dissolution of nubby ferric oxide by acidic porewater. Leaching coefficient was introduced to better express the response of element mobility to the degree of pyrite weathering. Its variation shows that the mobility of S, Co and Bi is stronger than As, Cu and Zn. Sulfur in pyrite is oxidized to sulfuric acid and sulfate that are basically released into to porewater, and heavy metals Co and Bi are evidently released by acid dissolution. As, Cu and Zn are enriched in ferric oxide by adsorption and by co-precipitation, but they would re-release to the environment via desorption or dissolution when porewater pH becomes low enough. Consequently, Co, Bi, As, Cu and Zn may pose a substantial impact on water quality. Considering that metal mobility and its concentration in mine waste are two important factors influencing heavy metal pollution at mining-impacted sites, Bi and Co are more important pollutants in this case.

Keywords: Environmental implications; Element mobility; Pyrite weathering』

Introduction
Site description
Materials and methods
 Element mobility index: leaching coefficient
Results and discussion
 Alteration layers of the weathered pyrite
 Environmental mobility and its environmental effect
 Mechanism of element transfer or transport
Conclusions
Acknowledgements
References


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