『Abstract
Mineralogy and chemical properties of the fine earth and particle
size fractions were examined with total chemical analysis, selective
chemical analyses and X-ray diffraction. Clay minerals were investigated
using microprobe and transmission electron microscopy. The chemical
changes during soil formation were calculated from results of
the chemical weathering mass balance. The study soil is of the
brown acid type, unsaturated and poor in short-range ordered products.
All soil fractions sized between 0 and 1 cm originate from transformation
of the weathered rind developed around tuff stones, where chemical
weathering is intense. The same weathering reactions which were
initiated in the early stages of tuff weathered rind were continued
in the soil with strong dissolution of plagioclases and transformation
of biotite. Two chemical weathering reactions led to the formation
of clay minerals in the soil: the precipitation of kaolinite into
biotite pseudomorphs and into the small white mica and the transformation
of the biotite (BI) into hydroxy-interlayered vermiculite (HIV)
with intermediary stages shown in HIV-BI interstratified minerals,
which were defined (95-75% of biotite layers). Pure vermiculite
or V-BI interstratified minerals were hydoxy-interlayered, even
in the weathered rind of the tuff. The chemical and mineralogical
mass balance between the weathered rind and the soil shows a heavy
dissolution of andesine (90%) and to a lesser extent of albite
(55%) and of apatite (60%), a precipitation of kaolinite and a
transformation of biotite into HIV. The plagioclase dissolution
in weathered tuff was almost complete, while there were only traces
remaining in silt. The biotite has almost disappeared in the fine
earth fractions due to dissolution and transformation into HIV.
Keywords: acid brown soil; mineral evolution; hydroxy-interlayered
vermiculite; kaolinite; chemical mass balance』
1. Introduction
2. Material and methods
2.1. Study area
2.2. Methods
3. Results
3.1. General soil characteristics (Table 2)
3.2. Mineralogy
3.2.1. Clay fractions
3.2.2. Coarse sand fractions
3.2.3. Chemistry of the secondary minerals
4. Discussion
4.1. Mineralogy of particle size fractions
4.1.1. Short-range ordered minerals
4.1.2. Weathering processes of primary minerals into crystalline
clay minerals in the soil
4.1.3. Inherited minerals and their evolution in the soil
4.2. Formation of soil from weathered rind
5. Conclusion
Acknowledgements
References