『Abstract
The geochemical study of the Dankar, Thinam and Gete lakes of
the Spiti Valley has revealed that these lakes are characterized
by varying contents of major ions, i.e. Ca, Mf, HCO3,
Na, K, Cl, SO4, SiO2
and Sr as trace element. The concentration of these elements is
significant, as they indicate the nature of the lithology and
the type of weathering at the source. The sediment chemistry data
have also been employed to quantify weathering intensity and to
elucidate the provenance and basin tectonic setting where terrigenous
sediment is deposited. Dankar Lake is located on the limestone-dolomite-rich
Lilang Group of rocks (Triassic), and dissolution of carbonate
is the prime source of ionic concentration in this lake. The high
(Ca+Mg) : HCO3 equivalent ratio of 6.94 indicates
carbonate weathering, and the very low (Na+K) : Tz+
ratio of 0.07, which is used as an indicator of silicate weathering,
shows insignificant silica dissolution in this lake. On the other
hand, in Lake Thinam a relatively low (Ca+Mg) : HCO3
equivalent ratio of 2.09, a (Na+K) : Tz+
ratio of 0.12 an other parameters indicate that carbonate is derived
from calcareous nodules and thin intercalations of limestone in
the Spiti shales (Jurassic), and also some contribution from silicate
lithology is evident.
Mixing of groundwater cannot be ruled out, as springs are observed
in this lake. In Lake Gete, the (Ca+Mg) : HCO3
equivalent ratio is again high at 5.04, and the (Na+K) : Tz+ ratio is 0.15, indicating dissolution
of both carbonate and silicate rocks in the basin. This is consistent
with the corresponding lithology in the lakes, and their denudation.
Very high Sr contents of 2,331μg/l in Dankar Lake, 715μg/l in
Gete Lake and 160μg/l in Thinam Lake are significant and support
dissolution of carbonate rocks, as the silicate rocks contribute
less Sr although its isotopic ratio is high. It is also reflected
that mechanical erosion and chemical weathering are perhaps the
effective processes in this region. The former exposes fresh mineral
surface for dissolution. The chemical index of alteration (CIA),
with an average value of 78.79 in Dankar and 81.06 on Gete, indicates
high weathering conditions. The K2O-Fe2O3-Al2O3 triangular plots of the samples demonstrate
residual clay formation, indicating intense weathering at the
source. The clay mineralogical fata corroborate the above observation.
The sediment chemistry data document depletion in SiO2
and Al2O3, as they are
enriched in carbonates and depleted in Na2O,
K2O, MnO, and TiO2,
as compared to PAAS and UCC which are related to strong weathering
at the source. The positive linear correlation between K and Rb
suggests that they are contained in the illitic phase, and high
positive correlation of Zr and Y with SiO2
indicates their association with coarser-grain, quartz-rich sandstone.
The high phyllosilicates and low feldspar and major element chemistry
indicate recycling and mineral maturity of sediments deposited
in the Tethyan basin in a passive margin setting. This also indicates
older sedimentary-metasedimentary rocks which are ideally exposed
in the Spiti Valley. The tectonic discriminant plots portray a
passive margin tectonic setting of the detritus in these lakes.
Keywords: Water and sediment chemistry; Provenance; Tectonic setting;
Spiti Valley; India』
Introduction
Geomorphic features and geology of the catchment area
Materials and methods
Water chemistry of the Spiti lakes
Sediment chemistry
Weathering and provenance
Tectonic setting
Conclusions
Acknowledgements
Reference