『Abstract
Base cation (BC) concentrations of rain, throughfall, percolation
from leaf litter, and soil solution were periodically measured
in two forests: Kannondai (red pine stand on volcanic soil) and
Yasato (deciduous stands on granitic soil). Calculation of a BC
budget gave the rate of BC release from soils; the BCs originated
from mineral weathering and cation exchange. Weathering rates
under field conditions were estimated from the Sr isotope ratios
(87Sr/86Sr) of water and soil samples. Isotope
ratios decreased in the order rain>throughfall>percolation>soil
solution. Clay and silt had extremely high isotope ratios; this
suggests that the sandy fraction, whose isotope ratio was smaller
than that of the soil solution, was the main contributor to mineral
weathering. estimated BC weathering rates (kmolc・ha-1y-1)
were 1.16 for Ca and 0.57 for Mg at Kannondai, and 0.82 for Ca
and 0.51 for Mg at Yasato. The unexpected high weathering rate
of granitic soil in Yasao was due to the wide coverage of the
original parent material by volcanic ash. The contribution of
cation exchange derived by subtraction was a little smaller than
the weathering rates and was similar to the values estimated from
a dynamic model that we developed.
Keywords: mineral weathering; neutralizing capacity; Sr isotope
ratio; BC budget; dynamic model』
1. Introduction
2. Materials and methods
2.1. Field measurement
2.2. Estimation of the weathering rates and base cation budget
2.3. Estimation of soil chemical changes with a dynamic model
3. Results and discussion
3.1. Ion budget estimation from field measurements
3.2. Weathering rate estimation based on Sr isotope ratios
3.3. Estimation of changes in exchangeable cations with a dynamic
model
4. Conclusions
Acknowledgements
References