『Abstract
Understanding the controls on chemical weathering, especially
of silicate minerals, remains a major challenge, despite its importance
in controlling the evolution of the Earth's surface. In particular,
it has proved hard to distinguish the temperature sensitivity
of silicate weathering rates from other factors. Here we present
a new compilation of chemical and physical erosion rates in small
catchments and show that silicate weathering rates are not governed
by any single parameter but require consideration i multiple dimensions.
The overall variation in silicate weathering rates with physical
erosion rates, rainfall, and temperature can be quantitatively
described by a parameterization based on considering their limiting
relationships. At lower erosion rates mineral supply limits weathering.
At higher erosion rates there is abundant material but kinetic
and therefore climatic factors limit weathering. A predictive
model describing the field data based o transport and weathering
(kinetically) cations from weathering is directly proportional
to the supply of material by erosion, consistent with complete
leaching of cations from fresh regolith. In the kinetically limited
case, weathering scales directly with runoff, as the square root
of erosion rate, and with an activation energy of 74±29 kJ/mol,
consistent with expected values in the Earth's surface settings.
Keywords: weathering; erosion; CO2; climate
change; feedback; transport-limited』
1. Introduction
2. Methods of data compilation and analysis
2.1. Data source
2.2. Setting
2.3. Calculation of weathering fluxes
2.4. Calculation of physical erosion fluxes
3. Results
4. Discussion
4.1. Limits on silicate weathering rates: transport limitation
4.2. Limits on silicate weathering rates: kinetic limitation
4.3. Variability of kinetic thresholds and time scale of weathering
5. Conclusions
Acknowledgements
Appendix A. Least-squares fitting
References