Schaef,H.T. and McGrail,B.P.(2009): Dissolution of Columbia River Basalt under mildly acidic conditions as a function of temperature: Experimental results relevant to the geological sequestration of carbon dioxide. Applied Geochemistry, 24, 980-987.

『温度の関数としての弱酸性条件下でのコロンビア川玄武岩の溶解:二酸化炭素の地質学的隔離に関連した実験結果』


Abstract
 Increasing attention is being focused on the rapid rise of CO2 levels in the atmosphere, which many believe to be the major contributing factor to global climate change. Sequestering CO2 in deep geological formations has been proposed as a long-term solution to help stabilize CO2 levels. However, before such technology can be developed and implemented, a basic understanding of H2O-CO2 systems and the chemical interactions of these fluids with the host formation must be obtained. Important issues concerning mineral stability, reaction rates, and carbonate formation are all controlled or at least significantly impacted by the kinetics of rock-water reactions in mildly acidic, CO2-saturated solutions. Basalt has recently been identified as a potentially important host formation for geological sequestration. Dissolution kinetics of the Columbia River Basalt (CRB) were measured for a range of temperatures (25-90℃) under mildly acidic to neutral pH conditions using the single-pass flow-through test method. Under anaerobic conditions, the normalized dissolution rates for CRB decrease with increasing pH (3≦pH≦7) with a slope, η, of -0.15±0.01. Activation energy, Ea, has been estimated at 32.0±2.4 kJ mol-1. Dissolution kinetics measurements like these are essential for modeling the rate at which CO2-saturated fluids react with basalt and ultimately drive conversion rates to carbonate minerals in situ.』

1. Introduction
2. Literature summary
3. Experimental materials and methods
 3.1. CRB sample collection chemical composition, and characterization
 3.2. CRB preparation and determination of specific surface area
 3.3. Buffer solution composition
 3.4. Single-pass flow-through method
 3.5. Influent and effluent solution analysis
 3.6. Quantification of dissolution rates
4. Results
 4.1. Achievement of steady-state
 4.2. Dissolution kinetics
5. Conclusions
Acknowledgments
References



戻る