Chairat（iの頭は¨）,C., Schott,J., Oelkers,E.H., Lartigue,J.-E. and Harouiya,N.(2007): Kinetics and mechanism of natural fluorapatite dissolution at 25℃ and pH from 3 to 12. Geochimica et Cosmochimica Acta, 71, 5901-5912.

『25℃および3～12のpHでの天然産フッ素燐灰石の溶解のカイネティックスとメカニズム』

『Abstract
　The dissolution rates of natural fluorapatite (FAP), Ca10(PO4)6F2, were measured at 25℃ in mixed-flow reactions as a function of pH from 3.0 to 11.7, and aqueous calcium, phosphorus, and fluoride concentration. After an initial preferential Ca and/or F release, stoichiometric Ca, P, and F release was observed. Measured FAP dissolution rates decrease with increasing pH at 3≦pH≦7, FAP dissolution rates are pH independent at 7≦pH≦10, and FAP dissolution rates again decrease with increasing pH at pH≧10. Measured FAP dissolution rates are independent of aqueous Ca, P, and F concentration at pH≒3 and pH≒10.
　Apatite dissolution appears to be initiated by the relatively rapid removal from the near surface of F and the Ca located in the M1 sites, via proton for Ca exchange reactions. Dissolution rates are controlled by the destruction of this F and Ca depleted surface layer. The destruction of this layer is facilitated by the adsorption/penetration of protons into the surface at acidic conditions, and by surface hydration at neutral and basic conditions. Taking into account these two parallel mechanisms, measured fluoapatite forward dissolution rates can be accurately described using
　r+(mol m-2 s-1) = 6.61×10 -6〔aH+Kads／（1 + aH+Kex + aCa2+4aF-1.4aOH-0.6/aH+6Kex）〕 + 3.69×10-8１ [≡CaOH2+]0.6±0.1
where ai refers to the activity of the ith aqueous species, [≡CaOH2+] denotes the concentration of hydrated calcium sites at the surface of the leached layer (mol m-2), and Kex and Kads stand for the apparent stability constants of the Ca2+/H+ exchange and adsorption/penetration reactions, respectively.』

1. Introduction
2. Theoretical considerations
3. Materials and methods
　3.1. Fluorapatite samples
　3.2. Dissolution rates measurements
4. Results
　4.1. Stoichiometry of fluorapatite dissolution
　4.2. pH dependence of fluorapatite dissolution rates
　4.3. The effect of solution composition on fluorapatite dissolution rates
5. The fluorapatite dissolution mechanism
　5.1. Neutral and basic solutions
　5.2. Acidic solutions
6. Concluding remarks
References


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