Satoh,H., Nishimura,Y., Tsukamoto,K., Ueda,A., Kato,K. and Ueta,S.(2007): In-situ measurement of dissolution of anorthite in Na-Cl-OH solutions at 22℃ using phase-shift interferometry. American Mineralogist, 92, 503-509.

『相シフト干渉計を用いた22℃でのNa-Cl-OH溶液における灰長石の溶解の原位置測定』


Abstract
 In-situ measurement of anorthite dissolution in Na-Cl-OH solutions at an ionic strength (IS) of 0.5 mol/L (M) and in artificial seawater (IS=0.7M) were conducted at 22℃ using white-light, phase-shift interference microscopy (PSI-M). Nanometer-scale surface topography by PSI-M revealed three-dimensionally inhomogeneous surface dissolution, which is commonly observed as retreating steps on anorthite surfaces. Continuous dissolution of the anorthite cleavage surface (010) was successfully measured within a day. The vertical dissolution velocity was 4.3×10-5 to 1.4×10-3 nm/s. The obtained dissolution rates showed a typical dependency on pH with a reaction order of 0.191, and could be consistently extended to the previous data obtained under acidic conditions (Luttge et al. 1999). In-homogeneities in the vertical dissolution velocities at each pH condition could be interpreted by the step dynamics explained by the Burton-Cablera-Frank (BCF) theory (Burton et al. 1951). These results emphasize that the velocity of step retreat is a strong function of the step density, whichhas to be taken into account when describing the global dissolution phenomena on mineral surfaces.

Keywords: Interferometry; dissolution; anorthite; step dynamics』

Introduction
 Optical method
 Reference for PSI measurement
Experimental methods
Results
Discussion
 Rate law
 pH dependency
 Dissolution mechanisms based on step dynamics
Acknowledgments
References cited



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