『Abstract
Rare earth element (REE) geochemistry and mineralogy have been
studied in the weathered crusts derived from the Early Yanshanian
(Jurassic) biotite granites of Dabu and Dingnan, as well as in
the Indosinian (Permian) muscovite-biotite granite of Aigao in
southern Jiangxi province, China, and the weathered crusts and
clay sediments on biotite granites in the Sanyo belt, SW Japan,
this is , Okayama, Tanakami, and Naegi areas. In all of the weathered
crusts, biotite and plagioclase commonly tend to decrease toward
the upper part of the profile, whereas kolinite and residual quartz
and K-feldspar increase. The weathered crusts of the Dingnan granites
and some Naegi granites, which are characterized by the enrichment
in light REE (LREE) in C horizons, have higher total REE (ΣREE)
content than the parent REE-enriched granites. Weathering of LREE-bearing
apatite and fluorocarbonates in the Dingnan granites and allanite
and apatite in some Naegi granites may account for the leaching
of LREE at the B horizons. The leached LREE must result in subsequent
enrichment of LREE in the C horizons. The enrichment is probably
associated with mainly adsorption onto kaolinite and partly formation
of possible secondary LREE-bearing minerals. In Japan it was found
that REE mineralization occurs not in the weathered granitic crusts
but reworked clay sediments, especially kaolinite-rich layers,
derived mainly from the weathering materials of REE-enriched granitic
rocks. The clay sediments are more enriched in LREE, which likely
adsorbed onto kaolinite. Concentration of heavy REE within almost
all the weathered crusts and clay sediments, however, may reflect
mainly residual REE-bearing minerals such as zircon, which originated
in the parent granitic rocks. The findings of the present study
support the three processes for fractionation of the REE during
weathering: (i) selective leaching of rocks containing both stable
and unstable REE-bearing minerals; (ii) adsorption onto clay minerals;
and (iii) presence of possible secondary LREE-bearing minerals.
Keywords: clay sediment; ion-adsorption-style REE deposit; mineral
resources; Jiangxi Province; rare earth element; Sanyo Belt; granitoids;
soil; weathered crust.』
1. Introduction
2. Geology
2.1. Granitoids in southern China
2.2. Granitoids of the Sanyo Belt
3. Samples and analyses
4. Results
4.1. Occurrence of weathered crust and clay sediment
4.2. X-ray diffraction identification of minerals
4.2.1. Weathered crusts of the Early Yanshanian granites in
southern China
4.2.2. Weathered crust of the Sanyo granitoids
4.2.3. Clay sediment in the Tanakami and Naegi areas
4.3. Chemical composition
4.3.1. Major elements
4.3.2. Rare earth elements and trace elements
4.3.3. Total REE content in weathered crusts and clay sediments
5. Discussion
5.1. Relationships between major elements and constituent
minerals in the weathered crusts
5.2. REE behavior in the weathered crusts
5.3. REE behavior in the clay sediments
5.4. Possible controlling factors for enrichment of REE and comparison
with ion adsorption-style deposit
6. Conclusions
Acknowledgments
References