『Abstract
A dynamical model (MAGic) is presented that describes the elemental
cycling of sedimentary materials involving sodium, potassium,
calcium, magnesium, chloride, carbon, oxygen, iron, sulfur and
phosphorus through much of the Phanerozoic. The model incorporates
the basic reactions controlling atmospheric carbon dioxide and
oxygen concentrations, continental and seafloor weathering of
silicates and carbonate rocks, net ecosystem productivity, basalt-seawater
exchange reactions, precipitation and diagenesis of chemical sediments
and authigenic silicates, oxidation-reduction reactions involving
carbon, sulfur, and iron, and subduction-decarbonation reactions.
Although MAGic contains feedback and forcing functions adapted
from the GEOCARB models (Berner, 1991, 1994; Berner and Kothavala,
2001), these functions are incorporated in a reservoir-reaction
scheme that is considerably more detailed. Coupled reservoirs
include shallow and deep cratonic silicate and carbonate rocks
and sediments, seawater, atmosphere, oceanic sediments and basalts,
and the shallow mantle. Model results are reasonably consistent
with recently published constraints provided by fluid inclusion,
isotopic, floral, and mineralogical records. We have used these
results to evaluate sensitivity to uncertainties in the history
of the earth-ocean-atmosphere system over the past 500 Ma: the
advent of pelagic carbonate sedimentation, the importance of burial
versus early diagenetic dolomite formation, the importance of
reverse weathering, and the relationship of these processes to
seafloor spreading rates. Results include a general pattern of
dolomite abundance during periods of elevated seafloor spreading
and alkalinity production, elevated atmospheric CO2
concentrations for most of the Phanerozoic similar to those predicted
by GEOCARB, and covariance of seawater sulfate to calcium ratios
with magnesium to calcium ratios. These trends are broadly consistent
with proxies for seawater composition and the mass-age data of
the rock record itself.』
Introduction
Model organization
Study sate fluxes
Continental weathering fluxes and CO2
Diagenetic and reverse weathering fluxes
Seawater saturation state, model operation, and notation
Calcium-magnesium-silicate-carbonate-CO2
subcycle
Sodium-potassium-silicate-carbonate-chloride-CO2
subcycle
Organic carbon subcycle
Sulfur subcycle
Iron and phosphorus subcycle
Model results and discussion
Atmospheric CO2 and the basalt carbonate buffer
MAGic standard run
Relationship to sulfate
The role of spreading rate
Dolomite distribution and reverse weathering
Productivity, phosphorus, and carbon burial
Conclusion
Acknowledgments
Appendix
Table A1 Principal fluxes
Table A2 Net atmospheric fluxes
Table A3 Model differential equations and steady state values
References