『Abstract
Phosphate (P) sorption and desorption characteristics have been
investigated for sixty-two representative samples of the major
Thai upland agricultural soils which are Oxisols and Ultisols
formed on diverse parent materials and under various climatic
conditions. P sorption characteristics are well described by Langmuir
and Freundlich equations. Values of Langmuir P sorption maximum
(Xm) and b coefficient range from 47 to 1250
μg g-1 soil and 0.5 to 30 mL μg-1, respectively
and the Freundlich k varies between 12 and 1694 μg g-1
and B coefficient 0.09 and 0.67. Soils derived from basalt have
larger values of P sorption maximum than soils on other parent
materials. Both P sorption maximum and Freundlich k are closely
related to pH (NaF), SSA, total titanium, aluminum and iron, dithionite
and oxalate extractable Fe and Al, and other soil properties that
reflect specific surface area. Soil pH in NaF is highly effective
in predicting the P sorption capacity of Thai upland soils explaining
79% of the variation in P sorption by these soils. P desorption
curves for adsorbed P are well described by the Freundlich equation.
The Freundlich kd coefficient for P desorption
is highly, linearly related to the Freundlich k coefficient of
P sorption indicating that the above soil factors that contribute
to P sorption similarly affect P desorption.
Keywords: Kaolinite; Iron oxides; pH (NaF); Ultisols; Oxisols;
Tropical soils』
1. Introduction
2. Materials and methods
2.1. Soil sampling and characterization
2.2. Phosphate adsorption and desorption
3. Results and discussion
3.1. Soil characteristics
3.2. Phosphate sorption coefficients
3.3. Phosphate sorption coefficients in relation to soil properties
3.4. Phosphate desorption
4. Conclusions
Acknowledgments
References