『Abstract
The chemistry of recent fish scales (tench, common carp, amur
and European perch) and subrecent fish scales (European perch
and mostly taxonomically not determined) was studied by means
of laser ablation inductively coupled plasma mass spectrometry
and electron microprobe from shallow boreholes in the abandoned
meander Certak near Uherske(後のeの頭に´) Hradiste.
A detailed study of subfossil fish confirms extremely rapid changes
in the chemical composition of hydroxylapatite during very early
diagenetic processes in the first 2 years, which does not change
significantly in the bottom of the boreholes about 25 years old.
While there is an enormous increase in Na, K, Ba and Sr, Fe and
Mn, there is a major decrease in Mg. The fish scales from 70 to
78 cm (6-8 years old) are approaching already the level of francolite-type
hydroxylapatite. The high Na content indicates carbonate substitutions
for OH or PO4 group. Consequently, environmental
interpretations based on the chemistry of fossil hydroxylapatites
require extreme caution. In recent fish scales, the element concentrations
reflect not only the position in the trophic pyramid but also
a complicated interplay of the diet, physiological processes and
environmental contamination.
Keywords: Hydroxylapatite; Fish scale; LA-ICP-MS; Diagenesis;
Trophic web; Abandoned meander; Morava River』
Introduction
Materials and geological setting
Methods
Sample preparation
Laser ablation ICP MS
Electron microprobe
Terminology for apatite
Results
Sediment
Fish scales
Discussion
Fluorine
Iron and manganese
Barium and strontium
Magnesium
Calcium
Alkali metals
Heavy metals
Conclusions
Acknowledgments
References