wAbstract
@Three novel composite adsorbents, sulfate-coated zeolite (SCZ),
hydrotalcite (SCH), and activated alumina (SCAA), were characterized
and employed for the removal of phosphate from aqueous solution
using equilibrium and kinetic batch experiments. Scanning electron
microscopy, Fourier transform infrared spectroscopy, and X-ray
diffraction spectrum were used to study the surface characteristics
of the coated layer. Equilibrium tests showed that the adsorption
of phosphate followed both Langmuir and Freundlich isotherms.
The powder-type SCZ was better for phosphate removal (maximum
binding energy, ΐ=11.49 mg g-1) compared to hydrotalcite
and activated alumina. The adsorption of phosphate was considered
to take place mainly by ion exchange. The kinetic data followed
a pseudo-second-order kinetic model. The initial adsorption of
phosphate onto the sulfate-coated adsorbents was fast, indicating
that the sulfate-coated materials developed in this study can
be used as promising adsorbents for the removal of phosphate from
wastewater or sewage.
Keywords: Sulfate coated; Zeolite; Hydrotalcite; Activated alumina;
Phosphatex
1. Introduction
2. Materials and methods
@2.1. Preparation of adsorbents
@2.2. Adsorption batch experiments
@2.3. Modeling of adsorption isotherm
@2.4. Analytical methods
3. Results and discussion
@3.1. Characteristics of the sulfate-coated and noncoated
adsorbents (SEM, XRD, FTIR)
@3.2. Equilibrium adsorption
@3.3. Kinetic adsorption
@3.4. Phosphate removal efficiency by the surface-modified adsorbents
4. Conclusions
Acknowledgments
References