wAbstract
@Simulated acidic precipitation (1:1 equivalent basis H2SO4:HNO3) at pH values of 2.5,
3.0, 3.5, 4.0, 4.5, 5.0 and 7.0 were conducted using column leaching
to determine impacts of simulated acid rain on phosphorus (P)
leaching from a calcareous sandy loam soil over a 40-day period.
Soil columns were irrigated every day to make a total of 1,061
mm, equivalent to 3.5 years of rainfall (based on average annual
rainfall). Leachates were collected and analyzed for anions and
cations. There was significant nonlinear correlation between the
amount of P leached and the simulated acid rain (R2
= 0.61). Losses of P from the pH 2.5 and 7.0 treatments were a.23,
and 1.32 mg kg-1, respectively. The results showed
that the amount of P leached from pH 4 (1.46 mg kg-1)
and 5 treatments (1.52 mg kg-1) were significantly
larger than other treatments. Linear equation adequately described
leaching of P in different treatments. The slope (mg kg-1
day-1) in the linear equation was defined as the leaching
rate and for the pH 2.5 was 0.0354 and 0.0382 and 0.0406 for pH
4.5 and 7.0, respectively. The geochemical code Visual MINTEQ
was used to calculate saturation indices. Leaching of P in different
treatments was controlled by rate-limited dissolution of hydroxyapatite,
ƒÀ-tricalcium phosphate and to some extent octacalcium phosphate.
The results indicate that acid rain in calcareous sandy loam soils
may pose a risk in terms of groundwater contamination with P.
Keywords: Acid rain; Phosphorus; Leaching; Calcareous soilsx
Introduction
Materials and methods
@Soil sample
@Simulated acid rain
@Leaching experiments
@Saturation indices
Results and discussion
@Leaching of P
@Phosphorus saturation index
Conclusions
Acknowledgments
References