wAbstract
@Excess PO43- from agricultural
subsurface drainage and runoff degrades the overall water quality
of the receiving surface waters in a cumulatively damaging process
known as eutrophication. In the past 25 years, PO43-
removal by industrial byproducts and minerals has received considerable
attention because these materials are both abundant and inexpensive.
In this study, the saturated falling-head hydraulic conductivity
and phosphate removal capability of granulated blast furnace slag
(GBFS), cement kiln dust (CKD), zeolite, silica sand, and coconut
shell activated carbon (CS-AC) were assessed. GBFS, zeolite, silica
sand, CS-AC, and 5:95 and 10:90 CKD/sand blends all exhibited
hydraulic conductivities0.001 cm/s. GBFS and the CKD/sand blends
exhibited98 PO43- removal while
CS-AS removed 70-79 of initial PO43-
concentrations. In contrast, silica sand and zeolite removed 21-58
of PO43-. The phosphate removal
data for each material was modeled against the Langmuir, Freundlich,
Temkin, Dubinin-Radushkevich, and Frumkin sorption isotherms to
yield insight into possible removal mechanisms. Overall, GBFS,
CKD, zeolite, silica sand, and CS-AC were sufficiently permeable
and removed significant amounts of PO43-
and should be considered for use in treatment of agricultural
effluent.
Keywords: Phosphate; Sorption; Industrial byproducts; Activated
carbon; Slag; Zeolitex
1. Introduction
2. Methods
@2.1. Industrial byproducts and minerals
@2.2. Saturated hydraulic conductivity
@2.3. PO43- sorption batch experiments
@2.4. Isotherm modeling
3. Results
@3.1. Hydraulic conductivity/permeability
@3.2. Batch-sorption experiments
@3.3. Isotherm model fits
4. Discussion
5. Conclusions
Acknowledgments
References