『Abstract
The potential of ferrihydrite-modified diatomite as a phosphorus
co-precipitant was investigated at a laboratory scale. Ferrihydrite-modified
diatomite was demonstrated to effectively remove phosphorus from
lake water as well as strongly bind phosphorus in sediment under
anoxic conditions. Phosphorus removal from the lake water proceeded
primarily through phosphorus adsorption onto ferrihydrite-modified
diatomite and further phosphorus consumption by stimulated diatom
growth. a total phosphorus removal efficiency of 85% was achieved
when lake water was dosed with 250 mg/L ferrihydrite-modified
diatomite; the residual total phosphorus concentration was 17.0μg/L,
which falls within the range for oligotrophic phosphorus levels.
During a 30-day anoxic incubation period, total phosphorus concentrations
in lake water treated with 400, 500, or 600 mg/L of ferrihydrite-modified
diatomite slightly decreased and maximum total phosphorus concentrations
remained below 15μg/L. Addition of ferrihydrite-modified diatomite
resulted in a marked increase in the iron-bound phosphorus fraction,
a pronounced decrease in labile phosphorus and organic-bound phosphorus
fractions, and stable aluminum-bound phosphorus, calcium-bound
phosphorus, and residual phosphorus fractions in the anoxic sediments.
Comparable iron-bound phosphorus concentration in the sediment
treated by 400 mg/L of ferrihydrite-modified diatomite relative
to that of the sediment treated by the combination of 400 mg/L
of ferrihydrite-modified diatomite and alum solution at the concentration
less than 532 mg/L indicated that ferrihydrite-modified diatomite
exhibited a stable phosphorus-binding capacity when dosed at a
similar amount. Ferrihydrite-modified diatomite had the potential
to be used as an effective phosphorus coprecipitant.
Keywords: Ferrihydrite-modified diatomite; Phosphorus removal;
Phosphorus release; Phosphorus co-precipitant』
1. Introduction
2. Materials and methods
2.1. Preparation of ferrihydrite-modified diatomite
2.2. Water and sediment samples
2.3. Phosphorus removal from lake water
2.4. Anoxic incubation of ferrihydrite-modified diatomite treated
sediments
2.5. Anoxic ferrihydrite-modified diatomite and alum treated
sediment incubation
2.6. Parameter measurements
3. Results and discussion
3.1. Removal of phosphorus from lake water
3.2. Anoxic incubation of lake water and sediment treated by
ferrihydrite-modified diatomite
3.3. Anoxic incubation of lake water and sediment treated by
ferrihydrite-modified diatomite and alum
4. Conclusions
Acknowledgments
References