『Abstract
Sequestering soil carbon (C) relies upon the availability of
stabilising elements, nitrogen (N), phosphorus (P) and sulphur
(S) which are known to be essential components of the stable organic
C pool (Himes, 1998; Lal, 2008). The C:N:P:S ratios were investigated
for a series of soils to test he hypothesis that the stable portion
of the soil organic material (humus) has constant ratios of C:N:P:S.
Constant ratios, if established, would provide an excellent tool
to evaluate the feasibility, cost and strategies to sequester
soil C in terrestrial ecosystems. Freshly-collected Australian
soils cited in the literature were analysed for total C, N, P,
organic P (OP) and S, and the ratios were compared with values
for soils from numerous locations around the world, hereafter
known as the International soils.
Total N and S were highly correlated with C for the International
and Australian soils and the relationships were similar for both
sets. The correlation of C with P for Australian soils was not
as strong as the correlations with N and S, however, a stronger
relationship was found for OP than P with C.
The correlation of OP with C for the International soils was
not as strong as for the Australian soils probably due, in part,
to the different methodologies used to analyse soil for OP in
the International soils compared with the single method used for
the Australian soils. The weaker relationship between OP and C
or both sets of soils, compared with the relationship between
N, S and C was probably also due, in part, to the wide variety
of compounds in the soil OP which vary in their relationship with
humus and the wide C:P ratio found in the soil microbial biomass.
Overall, the C:N:OP:S ratios were constant for the stable portion
of the soil organic material and these were consistent across
a wide range of global soils and should provide a reliable basis
with which to determine the level to which the availability of
N, P and S may limit humus-C sequestration in terrestrial ecosystems
although further research is needed to more accurately determine
the amount of OP in humus.
Keywords: Soil organic matter; Humus; C:N:P:S ratios; Carbon sequestration』
1. Introduction
2. Materials and methods
2.1. Definition of SOM and humus
2.2. International soils
2.3. Australian soils
2.4. Australian soil preparation - heavy/light material fractionation
2.5. Chemical analyses
3. Results
3.1. Fractionation procedure used on Australian soils
3.2. Analyses of International soils
3.3. Analyses of Australian soils
3.4. Comparison of C:N, C:OP and C:S ratios for Australian and
International soils
4. Discussion
4.1. Dies methodology matter?
4.2. Dealing with the LF
4.3. The ratios
4.3.1. C:N
4.3.2. C:S
4.3.3. C:OP
4.4. Implications for sequestering carbon in soil
Acknowledgements
References