wAbstract
@The phosphorus fractions in three tropical mangrove systems of
Cochin region were analysed by sequential extraction method. Iron-bound
phosphorus was the major fraction in the first two stations, while
station 3 was exclusively dominated by calcium-bound phosphorus.
Compared to other stations, about tenfold increase in total phosphorus
content was observed at station 3. This station is a congregation
of communally breeding birds, and there is accumulation of bird
guano. Mineralogical analysis showed the presence of monetite,
a thermodynamically metastable calcium phosphate mineral, in this
unique system. The excreta and carcass of the birds in this sanctuary
seems to be the reason for the formation of monetite, which is
favoured by periodic fluctuations in redox potential. The high
mass percentages of calcium and phosphorus by XRF and SEM-EDS
analysis confirm the existence of calcium phosphate mineral at
station 3. First two stations did not show any noticeable difference
in phosphorous fractions and inorganic fractions constituted to
about 65 of total phosphorus. But at station 3, inorganic fractions
were about 92. Low C:P ratios and low organic phosphorus content
indicated active mineralisation of phosphorus at station 3. Bioavailable
fractions of phosphorus at stations 1 and 2 were about 75, whereas
98 of the total phosphorus was bioavailable at station 3. Since
the bulk of the total phosphorus is available, these mangrove
sediments have the potential to act as source of phosphorus to
the overlying waters.
Keywords: Mangrove sediments; Phosphorus fractions; Sequential
extraction; Geochemistry; Guano; Monetitex
Introduction
Materials and methods
@Study area
@Sampling and analytical methodology
Results
Discussion
Conclusion
Acknowledgments
References