『Abstract
The adsorption of PO43- on lake
sediments has an important influence on the transport, degradation,
and ultimate fate of P in lake ecosystems. Organic matter in sediment
strongly affects PO43- adsorption,
with light fraction organic matter (LFOM), the labile fractions
representing only a small proportion of the total organic matter,
playing a key role in nutrient cycling in lakes. however, little
is known about the effect of LFOM on PO43-
adsorption by sediments. This study examined the effects of LFOM
removal on PO43- adsorption by
lake sediments with different trophic status. Results showed that
the removal of LFOM did not significantly affect PO43-
adsorption kinetics, which was greatest during the first 0.5 h
and reached an equilibrium state thereafter. The amount of PO43- adsorbed decreased due to LFOM
removal from the sediments, especially in the first 0.5 h. The
PO43- adsorption rates for the
sediments from Gonghu Lake, Wuli Lake and Yuehu lake decreased
from 302.44 mg (kg h)-1 to 138.93 mg (kg h)-1,
322.88 mg (kg h)-1 to 149.21 mg (kg h)-1
and 415.36 mg (kg h)-1 to 46.77 mg (kg h)-1,
respectively. The removal of LFOM accelerated PO43-
release from sediments to the overlying water, and PO43-
adsorption efficiency decreased by 83.75%, 70.90% and 66.75% for
Gonghu Lake, Wuli Lake and Yuehu Lake, respectively. Two plausible
explanations contributed to the decrease, one was the replacement
of PO43- which was in the form
of Fe/Al-bound P in the sediment by OH- due to the increased pH,
and the other is the destruction of LFOM colloids by the carboxyl
group (-COOH) and hydroxyl (-OH). 』
1. Introduction
2. Materials and methods
2.1. Sampling and analyses
2.2. Removal of organic matter from sediment samples
2.3. Adsorption isotherm
2.4. Adsorption kinetic measurements
2.5. Infrared spectroscopy
3. Results and discussion
3.1. Sediment characteristics
3.2. Effect of LEOM removal on PO43-
adsorption kinetics
3.3. Effect of LFOM removal on PO43-
adsorption isotherms
3.4. Infrared spectroscopy theory
4. Conclusions
Acknowledgements
References