『Abstract
The dissolution rates of natural, well crystallized variscite
(AlPO4・2H2O) were determined
from the evolution of aqueous Al and P concentrations in closed
and open-system mixed-flow reactors at 25℃ and pH from 1.5 to
9.0. Measured dissolution rates decrease with increasing pH, from
6×10-16 mol/cm2/s at pH 1.5 to 5×10-17
mol/cm2/s at pH 5.89, and then increase with increasing
pH to 4×10-16 mol/cm2/s at pH 9.0. Geochemical
modeling calculations, performed using measured dissolution rates,
indicate that it would take no more than a few weeks or months
to equilibrate a mildly acidic, Al and P-free solution with variscite.
Hence, variscite can buffer aqueous phosphate concentrations in
mildly acidic near surface environments. This conclusion is confirmed
by consideration of the compositions of natural waters.』
1. Introduction
2. Theoretical background
3. Materials and methods
4. Results
4.1. Closed-system experiments
4.2. Open-system experiments
5. Discussion
5.1. Variscite dissolution rates as a function of pH
5.2. Can variscite control the phosphate concentration of natural
waters?
6. Conclusions
Acknowledgments
Appendix A. Supplementary data
References