wAbstract
@In this study, organic carbon to organic phosphorus (Corg/Porg) and total phosphorus (Corg/Ptot) ratios as bottom water redox proxies are
explored for two eastern Mediterranean sediment records extending
back `600-700 kyrs. Cores KC19C (19.6 m long, 2750 m water depth)
and KC01B (37.0 m long, 3643 m water depth) contain numerous organic-rich
layers (sapropels). Throughout the two cores, variations found
in the Corg/P ratios correspond to those
for other redox proxies such as total S contents and V/Al ratios.
Accordingly, these are interpreted as variations in bottom water
oxygenation and inter-sapropel redox variability. In core KC19C,
the original Corg/P signals seem to have
been preserved despite intense post-depositional sulfidization.
High-resolution P fractionation data of sapropel S5 from a third
core (PS25PC, 3304 m water depth) showing high and relatively
stable Corg/Porg ratios,
indicate that sapropel S5 at this deep location was deposited
under permanently reducing conditions. While P regeneration from
organic matter was intense, net P burial increased in the sapropel
due to enhanced burial of inorganic calcium phosphate, likely
biogenic Ca-P. Sediment P contents and Corg/Ptot ratios in S5 are variable, reflecting short-term
changes in marine conditions (productivity/redox) and sediment
chemistry. The Corg/Porg
and Corg/Ptot ratios
thus provide valuable insight into paleoceanographic conditions
and pathways of P cycling for (Mediterranean) sediment records
extending back at least `600-700 kyrs.
Keywords: Phosphorus; C/P ratio; Redox proxy; Sapropel; S5; Mediterraneanx
1. Introduction
2. Materials and methods
@2.1. Core material
@2.2. Solid phase bulk analyses
@2.3. Phosphorus fractionation
@2.4. Fish debris counts
3. Results
@3.1. Bulk geochemistry of cores KC19C, KC01B and PS25PC
@3.2. Phosphorus fractionation in cores PS25PC and KC19C
4. Discussion
@4.1. Stability of Corg/P ratios on Quaternary
timescales
@4.2. Sediment Corg/P ratios: redox conditions
and P cycling during sapropel formation
@4.3. Redox conditions and phosphorus cycling during formation
of sapropel S5
5. Conditions
Acknowledgements
References