『Abstract
Phosphorus (P) species concentrations in 0-2 cm surface sediment
layer were investigated monthly from November 2001 to December
2002 at the bay, channel and open sea stations in the middle Adriatic.
Modified SEDEX method was used for inorganic phosphorus species
determination [P in biogenic (P-FD), authigenic (P-AUT), detrital
apatite (P-DET) and P adsorbed on to iron oxides and hydroxides
(P-Fe)], and organic phosphorus (P-ORG). P-FD, P-AUT and P-DET
concentration ranges (1.5-5.4, 0-2.7 and 0.4-3.4 μmol g-1,
respectively) were similar at all stations, and showed no obvious
common trend of seasonal changes. P-Fe ranged from 1.9 to 11.9
μmol g-1 with the highest values at bay station and
higher seasonal oscillations than other inorganic P forms. P-ORG
ranged from 0.3 to 18.7 μmol g-1 with higher concentrations
at stations of fine-sized sediments and showed increased concentrations
in warm part of the year at all stations. Correlation between
concentrations of P-Fe in the surface sediment layer and orthophosphate
sediment-water interface concentration gradients at bay and channel
stations indicated to P-Fe importance in the orthophosphate benthic
flux. For the bay station, linkage between sediment P-ORG and
chlorophyll a concentrations, primary production and microzooplankton
abundance was established, indicating a 1 month delay of sediment
response to production fluctuations in the water column.
Keywords: Sediment; Phosphorus species; SEDEX method; Adriatic
Sea』
Introduction
Materials and methods
Study area
Sampling and analytical determinations
Results and discussion
Orthophosphate (HPO42-) concentration
in the sediment pore water
Biogenic (P-FD), authigenic (P-AUT) and detrital (P-DET) apatite
phosphorus species concentrations in the sediment
Iron-bound phosphorus species (P-Fe) concentrations in the sediment
Organic P species (P-ORG) concentrations in sediments
Conclusions
References
※抽出法は、SEDEX法を改良したもの。