『Abstract
Amounts of phosphorus (P) in inorganic and organic pools were
determined for three noncalcareous and five calcareous surface
soils (0-150 mm) which had been cultivated for at least 15 yr,
and their virgin analogues, to ascertain if relative pool sizes
or soil P fertility are being changed by cultivation and associated
fertilizer application. The soils were representative of major
agricultural areas of the USA, with total P concentrations ranging
from 200 to 1920 mg kg-1 (approximately 50% inorganic
P ) and P applications from 0 to 90 kg ha-1 yr-1.
P forms in the pools and extractants used were as follows: inorganic
P; loosely-bound (1.0M NH4Cl), nonoccluded
(0.5M NH4F + 0.1M NaOH), occluded (citrate-dithionite-bicarbonate
+ 0.5M NH4F + 0.1M NaOH), and Ca bound (1.0M
HCl) (calcareous soils only): organic P; labile (0.5M NaHCO3), moderately labile (1.0M H2SO4 + 0.5M NaOH), moderately resistant (0.5M NaOH/HCl
soluble), and resistant (0.5M NaOH/HCl insoluble). Distribution
of inorganic P in virgin noncalcareous soils was, on average,
2% loosely-bound, 52% nonoccluded, and 46% occluded. Cultivation
resulted in an increase in nonoccluded and decrease in occluded
P. Average distribution in the virgin calcareous soils was 2%
loosely-bound, 11% nonoccluded, 9% occluded, and 78% Ca-bound,
with no significant change in pool size with cultivation observed.
On average, organic P in the virgin soils was 7% labile, 48% moderately
labile, 33% moderately resistant, and 12% resistant, with no significant
change in relative amounts due to cultivation. Amounts of fertilizer
P applied and organic P mineralized and immobilized in stable
inorganic P pools during cultivation, were related to P sorption
index of the soils. The conversion of organic to inorganic P may
be reversed by management practices allowing a build up of soil
organic matter. Since little change in amounts of loosely-bound
inorganic and labile organic P was observed during cultivation,
the more stable pools may represent a better estimate of long-term
soil fertility.
Additional Index Words: labile P; P mineralization; P sorption』
(Introduction)
Materials and methods
Results and discussion
Conclusions
References