『Abstract
The amount of potentially mobile phosphorus (P) in Lake Erken
sediments was determined by P release experiments, and forms of
mobile P were identified by P fractionation. Amounts and forms
of this P were compared to P released by sediment diagenesis.
Calculated on the top 30 cm of a sediment core, the amount of
potentially mobile P was 5 g/cm2, consisting mainly
of organic-P (NaOH-nrP) but also of P associated to iron (BD-P).
P release experiments were performed by maintaining steep diffusion
gradients in flow-through chambers under oxic or anoxic conditions.
Using this method it took no longer than three weeks to release
an amount of P from the main P mobile pools (NaOH-nrP, BD-P) corresponding
to P naturally lost during sediment diagenesis, a process which
normally takes years. Release rates as well as mobile amounts
of P in the NaOH-nrP pool varied significantly depending on the
redox status. In conclusion, the release method applied made it
possible to determine potentially mobile P under specified conditions
and to detect ecologically important P fractions in the surface
sediments.
Key words: phosphorus; sediment; diagenesis; release experiment;
P fractionation』
Introduction
Materials and methods
Release experiment design
Chemical analyses
Results
Phosphorus in the sediment profile
Release experiments
Discussion
Conclusion
Acknowledgements
References
堆積物試料 | 1M NH4Cl、pH 7で2.2時間 | NH4Cl−P『ゆるく吸着したP』(Loosely sorbed-P) | |
残渣 | 0.11M Na2S2O4/NaHCO3、1時間 | BD-P『Fe-P』 | |
残渣 | 0.1M NaOH、16時間 | NaOH−rP『Al-P』 | |
温浸(digestion) | NaOH−Tot P | ||
残渣 | 0.5M HCl、16時間 | HCl−P『Ca-P』 | |
残渣P(residual-P)(計算による)『Res-P』 |