Rydin,E.(2000): Potentially mobile phosphorus in Lake Erken sediment. Wat. Res., 34(7), 2037-2042.

『エルケン湖堆積物における潜在的に移動し易いリン』


Abstract
 The amount of potentially mobile phosphorus (P) in Lake Erken sediments was determined by P release experiments, and forms of mobile P were identified by P fractionation. Amounts and forms of this P were compared to P released by sediment diagenesis. Calculated on the top 30 cm of a sediment core, the amount of potentially mobile P was 5 g/cm2, consisting mainly of organic-P (NaOH-nrP) but also of P associated to iron (BD-P). P release experiments were performed by maintaining steep diffusion gradients in flow-through chambers under oxic or anoxic conditions. Using this method it took no longer than three weeks to release an amount of P from the main P mobile pools (NaOH-nrP, BD-P) corresponding to P naturally lost during sediment diagenesis, a process which normally takes years. Release rates as well as mobile amounts of P in the NaOH-nrP pool varied significantly depending on the redox status. In conclusion, the release method applied made it possible to determine potentially mobile P under specified conditions and to detect ecologically important P fractions in the surface sediments.

Key words: phosphorus; sediment; diagenesis; release experiment; P fractionation』

Introduction
Materials and methods
 Release experiment design
 Chemical analyses
Results
 Phosphorus in the sediment profile
 Release experiments
Discussion
Conclusion
Acknowledgements
References

図1.Psenner et al.(1988)に基本的に倣った、本研究で用いたリン分別法.(元は図)
堆積物試料 1M NH4Cl、pH 7で2.2時間 NH4Cl−Pゆるく吸着したP』(Loosely sorbed-P)
残渣 0.11M Na2S2O4/NaHCO3、1時間 BD-PFe-P
残渣 0.1M NaOH、16時間   NaOH−rPAl-P
温浸(digestion) NaOH−Tot P
残渣 0.5M HCl、16時間 HCl−PCa-P
残渣P(residual-P)(計算による)『Res-P


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