『Abstract
We used a sequential extraction technique and 210Pb
dating to determine the chemical form and amount of particulate
phosphorus (PP) that is retained during burial in 1-m-long sediment
cores collected along a salinity gradient from tidal freshwater
to the mesohaline waters of the Patuxent River, a subestuary of
the Chesapeake Bay. PP buried in the study sites with salinity
values ≦3 was similar in concentration and form to PP entering
the Patuxent from the watershed, suggesting efficient sequestration
by the sediments at these low-salinity sites. PP extracted with
citrate-dithionite-bicarbonate was the dominant form of PP at
all salinities and all depths, and organic-P was the second most
abundant fraction. we estimated that 81% of PP entering from the
watershed is trapped in the sediments of the upper Patuxent subestuary
and that the subtidal sediments retain three times as much PP
as the marshes adjacent to the study sites.
Keywords: Phosphorus; Sediments; Patuxent river; Chesapeake bay;
Citrate dithionite bicarbonate (CDB)』
Introduction
Study location
Methods
Sediment and pore water collection
Chemical analyses
Sediment characterization
210Pb dating
Results
Spatial variability of PP fractions
Spatial trends in CDB extractable Fe (CDB-Fe)
Sediment characterization
210Pb dating
Pore water solutes
Discussion
The fate of PP entering the upper Patuxent River subestuary
P burial rates
P burial in subtidal and marsh sediments
P budget for the Patuxent
Historical P loading
The Chemical forms of PP retained in the sediments
CDB-extractable P (Fe-P)
Organic-P
Authigenic CFA
Summary
Acknowledgements
References
※リンの連続抽出には、Ruttenberg(1992)のSEDEX法を修正したものを用いている。