『Abstract
The influence of reagent concentration, extraction time, and
lithological composition of sediment samples on the concentration
and composition of the extracted phosphorus fractions was examined.
Good reproducibility was achieved for dry samples. The proportions
of P fractions were found to depend on the texture of lake sediments,
which speaks about an essential role of cohesivity of sediments
and sorption of phosphorus in the sediment flocs. The NaOH-P concentration
was higher in the samples with a high silt content. Extraction
duration did not influence the concentration of metal oxide bound
P extraction with a low (0.1 M) NaOH concentration. The total
P concentration showed a significant positive correlation with
silt (r = 0.897), organic matter (r = 0.564), and carbonate content
(r = 0.546). Sedimentary inorganic P in the studied sediments
consisted mainly of HCl-P, while NaOH-P and NH4Cl-P
constituted only a minor part.
Key words: lake sediments; phosphorus fractions; lithological
composition.』
Introduction
Methods
Samples
Analyses
Results
Discussion
Conclusions
Acknowledgements
References
(4種類) |
|
|
0.1 g |
加熱(burning)550℃で3時間、 残渣:5 mLの0.5M HCl(塩酸)を加え、室温で48時間、 抽出⇒ |
P-tot (全P) |
0.1 g |
5 mLの0.5M HCl(塩酸)を加え、室温で24時間、 抽出⇒ |
HCl-P (アパタイトP) |
1 g |
10 mLの1M NH4Cl(塩化アンモニウム)を加え、室温で2時間振とう、 抽出⇒ 残渣:10 mLの1M NH4Cl(塩化アンモニウム)を加え、室温で2時間振とう、 抽出⇒ |
NH4Cl-P (ゆるく結合したP) |
1 g |
10 mLの0.1M NaOH(水酸化ナトリウム)を加え、室温で17時間振とう、必要ならH2SO4(硫酸)でフミン酸(humic
acid)を抽出、 抽出⇒ |
NaOH-P (金属酸化物結合P) |