wAbstract
@The Daliao river system in China has been seriously affected
by long-term intensive industrial, urban and agricultural activities.
The objectives of this study were to determine the total phosphorus
(TP) content and forms of phosphate in the sediments and investigate
geochemical relationships between P forms and sediment mineral
phases. Twenty-seven samples of surface sediments were collected
and analyzed for P and major elements. Chemical forms of phosphate
in the sediments were measured by sequential selective extraction
method. Results indicate that TP in the sediments of the Daliao
river system averaged 703 mg kg-1, in the range from
206 to 1,342 mg kg-1. The sediments in the tributaries
and near cities contained high TP, due to discharge of municipal
and industrial effluents. The distribution of phosphate in the
various mineral phases followed the order: Ca-PRES-PRS-PFe-PAl-PS/L-P
for the Hun river and Taizi river, and Ca-PFe-PRES-PRS-PAl-PS/L-P
for the Daliao river. Fe and Ca contents in the sediments were
positively correlated to Fe associated P (Fe-P and RS-P) and Ca-P,
respectively. In addition, sediment organic matter, Fe and Ca
contents were positively correlated to TP in the sediments. However,
al content was not correlated to Al-P or TP in the sediments.
Generally, the sediments contaminated by effluents and in tidal
zone contained more bioavailable P. Possible release of P from
these sediments to overlying water might pose potential risk on
estuarine eutrophication.
Keywords: Daliao river; Sediment; Phosphorus; Fractionation; Bioavailabilityx
Abbreviations
@S/L-P@Soluble and loosely bound P
@Al-P@Al bound P
@Fe-P@Fe bound P
@RS-P@Reductant soluble P
@Ca-P@Ca bound P
@RES-P@Residual P
@SOM@Sediment organic matter
Introduction
Materials and methods
@Sediment sampling and analysis
@Phosphorus fractionation
Results and discussion
@General properties of the sediments in the Daliao river systems
@Chemical forms of P in the sediments of the Daliao river system
@Relationships between P and mineral phases in the sediments of
the aliao river system
Conclusion
Acknowledgments
References