『Abstract
Phosphorus fractions and phosphate adsorption characteristics
of 16 sediments from a shallow freshwater lake (Nansi Lake, China)
and its inflow estuaries were investigated. In the present study,
the sediment phosphorus is fractionated into exchangeable P (exch-P),
Al-P, Fe-P, Ca-P, organic P (OP), inorganic P (IP) and total P
(TP). The results show that the total phosphorus (TP) content
in the sediments ranged from 571.67 to 1,113.55 mg kg-1,
and calcium bound phosphorus (Ca-P) is the main fraction of IP.
The biologically available phosphorus (BAP) ranges from 32.02
to 229.67 mg kg-1 in the Nansi Lake sediments. Phosphate
adsorption on the sediments mainly occurs within 10 h and is completed
within 48 h. The content of native adsorbed phosphorus (ωNAP) varies greatly from 6.05 to 194.37 mg kg-1,
showing a significant correlation with the total maximal amount
of phosphorus adsorbed (TQmax). Adsorption
efficiency (m) ranges from 574.79 to 3,220.68 l kg-1
and zero equilibrium phosphorus concentration (CEPC)
ranges from 9.919 to 0.157 mg l-1. After the South-to-North
Water Diversion Project, the inherent phosphorus present in sediments
will be a major threat to the diverted water quality and be a
predominant factor determining the trophic status of the lake
even if the external load is reduced.
Keywords: Inflow rivers; Nansi Lake; Phosphate adsorption; Phosphorus
fractions; Sediment
Introduction
Materials and methods
Study area
Sediment sampling and analysis
Phosphorus fractions and analysis
Phosphate adsorption kinetics experiments
Phosphate adsorption isotherm experiments
Results and discussion
Sediment characteristics
Phosphorus fractions
Phosphate adsorption kinetics
Characteristics of adsorption of phosphorus onto the sediment
Conclusions
Acknowledgements
References