『Abstract
Distribution and mobility of phosphorus in soil and sediment
are usually studied by sequential extraction. In the extraction
procedure, a sample is treated with a series of reagents to distinguish
the phases to which phosphorus is associated such as carbonate
and iron or manganese oxides, etc. There have been a number of
extraction schemes presented for phosphorus. At present, all of
the existing schemes are carried out batchwise. Phosphorus contents
derived from all sequences are operationally defined and depend
on experimental conditions.
An extraction procedure, which is a continuous-flow-based technique,
was recently proposed by our group for metals in soils and sediments.
The extraction is carried out in a closed chamber through which
extractants are passed sequentially. In this paper, the system
was investigated using the extraction scheme of Hieltjes and Lijklema
to study distribution of phosphorus in three certified reference
materials (CRMs). A number of fractions were collected for each
reagent for subsequent colorimetric determination. The results
are compared with those obtained from a batch extraction. The
summation of phosphorus contents of all phases were compared with
the certified values and with the values obtained from total digestion.
These results have demonstrated that the continuous extraction
system developed is also applicable for fractionation of phosphorus.
Advantage and disadvantage are discussed.
Keywords: Phosphorus; Sequential extraction; Continuous-flow system』
1. Introduction
2. Experimental
2.1. Chemicals
2.2. Sample
2.3. Sequential extraction
2.3.1. The batch procedure
2.3.2. The continuous-flow procedure
2.4. Procedure for phosphorus dissolution of sample and residue
3. Results and discussion
3.1. Validation of the method for phosphorus dissolution
3.2. Extractogram given by the continuous-flow extraction
3.3. Fractionation of phosphorus by the continuous-flow and the
batch procedures
3.4. Comparison between the continuous-flow and the batch procedures
3.5. Clogging of the in-line filter in the extraction chamber
4. Conclusions
Acknowledgements
References