(Introduction)
Experimental
Reagents
Standard phosphate solutions
Treatment of apparatus
Procedure
Beer's law and reproducibility
Salt error
Interferences
『Summary
A single solution reagent is described for the determination
of phosphorus in sea water. It consists of an acidified solution
of ammonium molybdate containing ascorbic acid and a small amount
of antimony. This reagent reacts rapidly with phosphate ion yielding
a blue-purple compound which contains antimony and phosphorus
in a 1 : 1 atomic ratio. The complex is very stable and obeys
Beer's law up to a phosphate concentration of at least 2μg/l.
The sensitivity of the procedure is comparable with that of the
stannous chloride method. The salt error is less than 1%.』
References