Murphy,J. and Riley,J.P.(1962): A modified single solution method for the determination of phosphate in natural waters. Anal. Chim. Acta, 27, 31-36.

『天然水中のリン酸塩の決定に対する修正した単一溶液法』


(Introduction)
Experimental
 Reagents
 Standard phosphate solutions
 Treatment of apparatus
 Procedure
 Beer's law and reproducibility
 Salt error
 Interferences

Summary
 A single solution reagent is described for the determination of phosphorus in sea water. It consists of an acidified solution of ammonium molybdate containing ascorbic acid and a small amount of antimony. This reagent reacts rapidly with phosphate ion yielding a blue-purple compound which contains antimony and phosphorus in a 1 : 1 atomic ratio. The complex is very stable and obeys Beer's law up to a phosphate concentration of at least 2μg/l. The sensitivity of the procedure is comparable with that of the stannous chloride method. The salt error is less than 1%.』

References


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