『Abstract
Suspended sediments collected during rain events were analysed
to assess the maximum potential bioavailability of particulate
phosphorus (PP). Physical (separation by particle size) and chemical
(sequential extraction) fractionation techniques were applied.
Time differentiated sampling during rain events revealed that
changes in the concentrations of soluble and particle bound phosphorus,
and in the proportion of different PP phases, are due to the changing
contribution of various sources of runoff and to flow related
variations in particle size. Size fractionation and the extraction
of PP phases, can help to distinguish resuspended sediments from
sediments coming directly from outside the channel. In light of
a formerly study, investigating PP sedimentation and transformations
within the sediments of Lake Sempach, our results lead to the
conclusion that, at least 25% (particulate inorganic and reductive
soluble P) and at most 70% of the allochthonous PP supply transported
during a single rain event, may become bioavailable after early
diagenesis in the lake sediments. The uncertainty is due to the
unknown time span necessary for the diagenesis, at the lake sediment
surface, of particulate organic phosphorus of allochthonous origin.
Keywords: sequential phosphorus extraction; suspended sediment;
size fractions; storm runoff』
Introduction
The Kleine Aa catchment
Methods
General sample treatment
Sequential P extraction
Results
Effect of the litter
Effect of phosphate adsorption
Streamwater and suspended sediment analysis
Sequential extraction of PP during storms
Particle size of suspended sediment
Fluxes
Discussion
Influence of particle size on P transport
The source of BD-P
The “iron curtain”
Fluxes of PP during storm events
Bioavailability
Conclusions and recommendations
Acknowledgments
References