Aydin,I., Aydin,F., Saydut,A. and Hamamci,C.(2009): A sequential extraction to determine the distribution of phosphorus in the seawater and marine surface sediment. Journal of Hazardous Materials, 168, 664-669.

『海水と海洋表層堆積物中のリンの分布を決定するための連続抽出』


Abstract
 The distribution of phosphorus species among environmental compartments (e.g., between water and sediment), significantly affects the bioavailability of these species to organisms. The eastern Mediterranean Sea is one of the most extreme oligotrophic oceanic regions on earth in terms of nutrient concentrations and primary productivity. The paper presents the results of inorganic and organic forms in surface sediment and seawater from NE Mediterranean Sea (Burclar Bay, Erdemli, South Anatolia of Turkey) in May 2007. Speciation of phosphorus in seawater and surface sediment using inductively coupled plasma-atomic emission spectrometer (ICP-AES) has been reported here. The method is based on sequential extractions of the seawater and sediment each releasing four forms of inorganic phosphorus: loosely sorbed phosphorus. phosphorus bound to aluminium (P-Al), phosphorus bound to iron (P-Fe) and phosphorus bound to calcium (P-Ca).
 The most abundant form of inorganic phosphorus in the seawater and surface sediment is calcium-bound phosphorus. Relative abundances of the remaining phosphorus forms in sediment follow the order: P-Al>P-Fe>loosely bound-P and in seawater follow the order P-Fe>P-Al>loosely bound-P.

Keywords: Sediment; Phosphorus; Speciation; Mediterranean Sea; Seawater』

1. Introduction
2. Experimental
3. Results and discussion
4. Conclusions
References

表3 海洋表層堆積物に対するリンの鉱物質化学種の平均値
  μg P/g
(±は標準偏差)

P-mineral
(鉱物質全リン)
201.23±2.13 100.00
P-Ca 161.61±1.02 80.31
P-Al 16.89±0.49 8.39
P-Fe 9.56±0.27 4.75
Loosely bound-P
(ゆるく結合したリン)
9.29±0.32 4.62

表5 海水に対するリンの鉱物質化学種の平均値
  μg P/g
(±は標準偏差)

P-mineral
(鉱物質全リン)
1.92±0.012 100.00
P-Ca 1.05±0.025 54.69
P-Fe 0.53±0.009 27.60
P-Al 0.11±0.003 5.73
Loosely bound-P
(ゆるく結合したリン)
0.02±0.001 1.04


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