『Abstract
Previous attempts to evaluate ocean P mass balance and residence
time have utilized sequential extraction techniques to isolate
and analyze P associated with Fe and Mn oxides and oxyhydroxides,
authigenic minerals, detrital, and organic phases. However, in
many oceanographic settings, diatoms are the primary producers,
and the traditional sequential extraction protocol does not result
in complete dissolution of diatom frustules and may not liberate
all of the opal intrinsic P associated with the frustules themselves.
By adding an opal dissolution step to the end of the extraction
protocol, additional P was liberated from the sediments, suggesting
that there is an opal-associated P fraction that likely contributes
to total reactive P concentrations. In opal-rich sediments, the
opal-associated P fraction averages as much as 50-60% of extractable
P, and total reactive P concentrations are often more than double
when the opal-associated P fraction is included. The presence
of opal-intrinsic P potentially has significant implications for
ocean P mass balance and residence time of P in the oceans. For
example, P burial has possibly been underestimated in settings
dominated by diatoms. Additionally, consideration of a significant
sedimentary opal-P component suggests that the residence time
of P in the oceans may be even shorter than currently suspected.』
1. Introduction
2. Study sites
3. Methods
4. Results and discussion
5. Phosphorus accumulation rates and opal-associated P
6. Implications
7. Conclusions
Acknowledgments
References
|
試薬 | 分離されたリン成分 |
酸化物に伴った |
10mL CDB溶液(6時間)(0.22Mクエン酸ナトリウム、1M炭酸水素ナトリウム、0.13M亜ジチオン酸ナトリウム)、 10mL 1M塩化マグネシウム(2時間)、 10mL水(2時間) |
吸着したおよび還元可能なあるいは反応しやすい鉄結合P(Adsorbed and reducible or reactive Fe-bound P) |
自生 |
酢酸でpH 4に緩衝した10mL 1M酢酸ナトリウム、 10mL 1M塩化マグネシウム(2時間)−2回、 10mL水(2時間) |
炭酸フッ素燐灰石(Carbonate fluorapatite、CFA)、 生物起源水酸化燐灰石(biogenic hydroxy apatite)、 CaCO3結合P |
砕屑性 | 10mL 1M塩酸(16時間) | 砕屑性P(Detrital P) |
有機 |
1mL 50%(w/v)硝酸マグネシウム、 オーブンで低温乾燥、 550℃で灰化(2時間)、 10mL 1M塩酸 |
有機P(Organic P) |
オパールに伴った |
10mL 1.5M水酸化ナトリウム(85℃、2時間)、 または、 10mL 1.5M水酸化ナトリウム(85℃、2時間)の後に10mL 2M炭酸ナトリウム(85℃、5時間) |
オパールに伴ったP(Opal-associated P) |
残渣(Residual) | 5mL硝酸、4mLフッ化水素酸、1mL塩酸 | 続く抽出ステップで残留するP(P remaining following extraction steps) |